DOI: 10.1016/j.jcou.2018.05.021
Scopus记录号: 2-s2.0-85047551777
论文题名: Recent applications of polyoxometalates in CO2 capture and transformation
作者: Yu B. ; Zou B. ; Hu C.-W.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2018
卷: 26 起始页码: 314
结束页码: 322
语种: 英语
英文关键词: Carbon dioxide capture
; Carbon dioxide fixation
; Polyoxometalates
Scopus关键词: Catalysts
; Oxides
; Urea
; Carbon dioxide capture
; Carbon dioxide fixation
; Cyclic carbonates
; Natural stability
; Polyoxometalates
; Renewable carbon sources
; Sustainable chemistry
; Sustainable technology
; Carbon dioxide
英文摘要: CO2 chemistry has drawn considerable attention as abundant, low cost, and renewable carbon source in the past decades. The natural stability of CO2 made its utilization a daunting challenge under mild conditions. Recently, there has been significant progress of CO2 fixation by using cheap and abundant functionalized polyoxometalate (POM) catalysts. In this review, the POM catalytic system for transformation of CO2 into valuable compounds such as urea, cyclic carbonate, quinazoline-2,4(1H,3H)-diones, α-methylene cyclic carbonate, oxazolidinones etc. were discussed. The future of POM catalysis for sustainable chemistry lies in the synthesis of highly functionalized task-specific POM catalysts, and rational design of novel reactions which would eventually pave the pathway for the establishment of green, effective, inexpensive and sustainable technologies. © 2018 Elsevier Ltd.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/111834
Appears in Collections: 气候减缓与适应
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作者单位: Key Laboratory of Cluster Science of Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China; College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan Province, 450001, China
Recommended Citation:
Yu B.,Zou B.,Hu C.-W.. Recent applications of polyoxometalates in CO2 capture and transformation[J]. Journal of CO2 Utilization,2018-01-01,26