DOI: 10.1016/j.jcou.2018.06.022
Scopus记录号: 2-s2.0-85049184778
论文题名: Formate dehydrogenase for CO2 utilization and its application
作者: Amao Y.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2018
卷: 26 起始页码: 623
结束页码: 641
语种: 英语
英文关键词: Biocatalyst
; CO2 utilization
; Electron mediator
; Formate dehydrogenase
; Photoredox system
Scopus关键词: Biocatalysts
; Catalyst activity
; Catalyst selectivity
; Environmental technology
; Formic acid
; Genetic engineering
; Light
; Reduction
; Electrochemical systems
; Electron mediator
; Environmental science
; Formate dehydrogenase
; Formic acid oxidation
; Photoredox system
; Potential technologies
; Visible-light-driven
; Carbon dioxide
英文摘要: Carbon dioxide, CO2 reduction and utilization for organic compounds synthesis are the potential technologies in environmental science and technology. In order to establish efficient CO2 utilization technologies, an effective catalyst for CO2 reduction and utilization is necessary. Among various catalysts, the biocatalyst is one of promising catalysts because it has excellent selectivity for the reaction and substrate. In this review, focusing on biocatalyst "formate dehydrogenase FDH" catalyzing CO2 reduction to formic acid, representative examples of properties, types, structure of active-site of FDH and, reaction mechanism of formic acid oxidation and CO2 reduction with FDH are outlined. A genetic engineering modified FDH and FDH immobilized various support for improving CO2 reduction catalytic activity also are introduced. Moreover, chemical and electrochemical system of CO2 reduction to formic acid with FDH, aqueous homogenous system of visible-light driven CO2 reduction to formic acid with FDH and device for visible-light driven CO2 reduction to formic acid with FDH are also introduced as an application of FDH. © 2018 Elsevier Ltd. All rights reserved.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/111835
Appears in Collections: 气候减缓与适应
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作者单位: Advanced Research Institute for Natural Science and Technology, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, 558-8585, Japan; Research Center for Artificial Photosynthesis (ReCAP), Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku Osaka, 558-8585, Japan
Recommended Citation:
Amao Y.. Formate dehydrogenase for CO2 utilization and its application[J]. Journal of CO2 Utilization,2018-01-01,26