DOI: 10.1016/j.jcou.2018.05.028
Scopus记录号: 2-s2.0-85048020302
论文题名: Amine-based CO2 capture sorbents: A potential CO2 hydrogenation catalyst
作者: Chakravartula Srivatsa S. ; Bhattacharya S.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2018
卷: 26 起始页码: 397
结束页码: 407
语种: 英语
英文关键词: Amine coverage
; Carbamate
; Carbamic acid
; CO2capture
; FTIR
Scopus关键词: Adsorption
; Amines
; Fourier transform infrared spectroscopy
; Organic acids
; Sorbents
; Thermogravimetric analysis
; Adsorption capacities
; Carbamate
; Carbamic acid
; CO2 concentration
; CO2 hydrogenation
; CO2capture
; FTIR
; Situ diffuse reflectance infrared Fourier transform spectroscopy
; Carbon dioxide
英文摘要: Mechanism of CO2 adsorption on amine loaded SBA-15 sorbents with varying amine coverage has been assessed using thermogravimetric analysis (TGA) and in-situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS). TGA study showed that sorbent adsorption capacities increased by 122-153% with CO2 concentrations (5-80%) in the gas at 50/75°C. The DRIFTS studies indicate that low amine loaded sorbents exhibit higher uptakes with an increase in CO2 concentrations which is attributed to the mode of CO2 adsorption i.e. 1:1 CO2 to amine forming carbamic acid. At higher amine loadings CO2 is adsorbed following the 1:2 CO2 to amine forming carbamate-ammonium ions pair resulting in lower adsorption capacities per amine site. The studies also showed an increase in carbamic acid formation with pressure from 100 to 500kPa at low amine loadings and both carbamic acid and carbamates at higher amine loadings. The paper provides insights into the mechanistic understanding of CO2 adsorption behaviour of the varyingly covered amines on the SBA-15 support with a change in concentration and pressure of CO2. The current work presents the conditions to alter the CO2 adsorption mechanism on amine sites with potential application in CO2 conversion to chemicals. © 2018 Elsevier Ltd. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/111891
Appears in Collections: 气候减缓与适应
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作者单位: Chemical Engineering Department, Monash University, Wellington Road, Clayton, VIC 3800, Australia
Recommended Citation:
Chakravartula Srivatsa S.,Bhattacharya S.. Amine-based CO2 capture sorbents: A potential CO2 hydrogenation catalyst[J]. Journal of CO2 Utilization,2018-01-01,26