globalchange  > 气候减缓与适应
DOI: 10.1016/j.jcou.2018.04.008
Scopus记录号: 2-s2.0-85045935726
论文题名:
Harnessing electron-rich framework in cyclophosphazene derived hybrid nanoporous materials for organocatalytic C-C bond formation and gas sorption applications
作者: Muhammad R.; Chaudhary M.; Mohanty P.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2018
卷: 25
起始页码: 302
结束页码: 309
语种: 英语
英文关键词: C-C bond formation ; Carbon dioxide capture ; Hierarchical pore structure ; Inorganic-Organic hybrid nanoporous materials ; Organocatalysis
Scopus关键词: Carbon dioxide ; Covalent bonds ; Nanopores ; Plasma interactions ; Pore structure ; C-C bond formation ; Carbon dioxide capture ; Hierarchical pore structures ; Nano-porous materials ; Organocatalysis ; Hybrid materials
英文摘要: Nanoporous inorganic-organic hybrid materials with estimated specific surface area (SABET) of 870 m2 g-1 and multimodal hierarchical pore structure centered at 1.64, 3.14 and 6.3 nm have been synthesized. These cyclophosphazene derived metal-free materials have adsorbed 14.8 and 1.61 wt% of CO2 and H2 at 273 and 77 K, respectively, at 1 bar. The materials have shown efficient C-C bond formation via the Knoevenagel condensation with a maximum yield of 97% that only reduced marginally to 81% even after five cycles. These electron rich high surface area materials could further be useful for several other energy and environmental applications. © 2018 Elsevier Ltd. All rights reserved.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/111909
Appears in Collections:气候减缓与适应

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作者单位: Functional Materials Laboratory, Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee, Uttarakhand, 247667, India

Recommended Citation:
Muhammad R.,Chaudhary M.,Mohanty P.. Harnessing electron-rich framework in cyclophosphazene derived hybrid nanoporous materials for organocatalytic C-C bond formation and gas sorption applications[J]. Journal of CO2 Utilization,2018-01-01,25
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