DOI: 10.1016/j.jcou.2018.01.015
Scopus记录号: 2-s2.0-85041811001
论文题名: Three component coupling of amines, alkyl halides and carbon dioxide: An environmentally benign access to carbamate esters (urethanes)
作者: Vessally E. ; Mohammadi R. ; Hosseinian A. ; Edjlali L. ; Babazadeh M.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2018
卷: 24 起始页码: 361
结束页码: 368
语种: 英语
英文关键词: Carbamate esters
; Carbon dioxide
; Carboxylative coupling
; Cs2CO3
; Three-component reactions
Scopus关键词: Amines
; Carbon dioxide
; Cesium compounds
; Esters
; Biological properties
; Cs2CO3
; Environmentally benign
; Sustainable chemistry
; Synthesis of carbamates
; Synthetic organic chemistry
; Three component reactions
; Three-component coupling
; Carbonyl compounds
英文摘要: Carbamate esters represent an important class of compounds showing a wide range of interesting biological properties. Such compounds exhibit anti-cancer, anti-HIV, anticonvulsant, antiretroviral, anti-nociceptive, anti-inflammatory, anti-Alzheimer, and antibiotic properties. Moreover, these compounds have many applications in the area of synthetic organic chemistry. Consequently, considerable efforts have devoted to the development of efficient and practical synthetic routes to these useful compounds. However, common preparations leading to these target compounds are limited by requiring toxic reagents such as phosgene, its derivatives, or isocyanates. Synthesis of titled compounds employing CO2 as a clean and safe carbonyl reagent in place of toxic phosgene or isocyanates has attracted considerable attention in recent years. In this mini-review we will highlight the most important developments on the synthesis of carbamate esters through the carboxylative coupling of amines with alkyl halides and CO2 by hoping that it will stimulate researchers to develop new and improved methods for the synthesis of these biologically and synthetically important compounds with sustainable chemistry and Green Chemistry perspectives. © 2018 Elsevier Ltd Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/111974
Appears in Collections: 气候减缓与适应
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作者单位: Department of Chemistry, Payame Noor University, Tehran, Iran; Department of Engineering Science, College of Engineering, University of Tehran, P.O. Box 11365-4563, Tehran, Iran; Department of Chemistry, Tabriz Branch, Islamic Azad University, Tabriz, Iran
Recommended Citation:
Vessally E.,Mohammadi R.,Hosseinian A.,et al. Three component coupling of amines, alkyl halides and carbon dioxide: An environmentally benign access to carbamate esters (urethanes)[J]. Journal of CO2 Utilization,2018-01-01,24