DOI: 10.1016/j.watres.2018.09.017
Scopus记录号: 2-s2.0-85053781080
论文题名: Recovery of polyphenols onto porous carbons developed from exhausted grape pomace: A sustainable approach for the treatment of wine wastewaters
作者: Nayak A. ; Bhushan B. ; Rodriguez-Turienzo L.
刊名: Water Research
ISSN: 431354
出版年: 2018
卷: 145 起始页码: 741
结束页码: 756
语种: 英语
英文关键词: Adsorption
; Chemical activation
; Exhausted grape pomace
; Polyphenols recovery
; Valorisation
; Wine wastewater
Scopus关键词: Activated carbon
; Activated carbon treatment
; Adsorption
; Anaerobic digestion
; Binding sites
; Chemical activation
; Chlorine compounds
; Cost effectiveness
; Dietary supplements
; Organic solvents
; Porosity
; Porous materials
; Recovery
; Wine
; Zinc chloride
; Electron donor acceptors
; Ethanol-water solvents
; Grape pomace
; Polyphenols
; Selective surface
; Simulated wastewater
; Total polyphenols
; Valorisation
; Wastewater treatment
; Vitaceae
英文摘要: Removal of total polyphenols (TPP) is not only necessary as a pretreatment stepfor anaerobic digestion of wine wastewaters (WWW) but also the recovered polyphenols can be used as a dietary supplement. With a view to make the process sustainable, eco-efficient and cost effective, exhausted grape pomace (EGP) after the extraction of polyphenols was impregnated with ZnCl2 (1:1.5) and further activated at 450 °C for 1 h under inert atmosphere. The GPAC (grape pomace activated carbon) thus developed exhibited well-developed porosity with a predominance of micropores, high surface area and selective surface binding sites. Batch adsorption conducted on diluted WWW revealed the better performance of GPAC (84.3% removal) as compared to EGP (48.5% removal) under similar conditions; with maximum adsorption taking place at pH 3.8. While pH studies indicated a possible electron-donor-acceptor mechanism in the binding of TPP, kinetic studies indicated that diffusion was mediated by the porosity in GPAC. Isotherm studies conducted on GPAC and commercial carbon (CAC) revealed multilayer binding under WWW while Langmuir model was operative under simulated conditions. Contrary to the better performance of CAC, the same for GPAC was comparable at higher dosage where >80%TPP was removed from undiluted WWW. The phenol adsorption capacity of GPAC from real (28.4 mg/g) and from simulated wastewater (142.6 mg/g) was higher as compared to other reported adsorbents. Desorption of TPP from loaded GPAC was maximum (∼91%) with 1:1 ethanol-water solvent. The results reveal a sustainable eco-friendly solution for valorisation of exhausted grape pomace for recovery of polyphenols from wine wastewater. © 2018 Elsevier Ltd Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/112465
Appears in Collections: 气候减缓与适应
There are no files associated with this item.
作者单位: Innovació i Recerca Industrial I Sostenible08860, Spain; Graphic Era University, Dehradun, 248002, India; Chemical Engineering Department, UPC-Barcelona TECH, Resource Recovery Processes and Technologies (R2PT) Barcelona Research Center for Multiscale Science and Engineering, C/Eduard Maristany 10-14, Campus Diagonal-Besòs, Barcelona, 08930, Spain
Recommended Citation:
Nayak A.,Bhushan B.,Rodriguez-Turienzo L.. Recovery of polyphenols onto porous carbons developed from exhausted grape pomace: A sustainable approach for the treatment of wine wastewaters[J]. Water Research,2018-01-01,145