DOI: 10.1016/j.watres.2018.05.050
Scopus记录号: 2-s2.0-85051756368
论文题名: Tradeoffs between pathogen inactivation and disinfection byproduct formation during sequential chlorine and chloramine disinfection for wastewater reuse
作者: Furst K.E. ; Pecson B.M. ; Webber B.D. ; Mitch W.A.
刊名: Water Research
ISSN: 431354
出版年: 2018
卷: 143 起始页码: 579
结束页码: 588
语种: 英语
英文关键词: Coliform
; Halogenated DBPs
; NDMA
; Potable reuse
; Sequential chlorination
; Virus
Scopus关键词: Amination
; Amines
; Ammonia
; Byproducts
; Chlorination
; Chlorine
; Disinfection
; Effluents
; Viruses
; Wastewater reclamation
; Wastewater treatment
; Water pollution control
; Coliform
; Coliform concentrations
; Disinfection by-product
; Disinfection byproducts
; Halogenated DBPs
; Maximum contaminant levels
; NDMA
; Potable reuse
; Chemicals removal (water treatment)
; ammonia
; chlorine
; tosylchloramide sodium
; trihalomethane
; bacteriophage
; biofouling
; byproduct
; chlorination
; chlorine
; coliform bacterium
; concentration (composition)
; disinfection
; effluent
; membrane
; pathogen
; toxicity
; virus
; wastewater
; wastewater treatment
; Article
; chlorination
; coliform bacterium
; contact time
; cytotoxicity
; disinfection
; Enterobacteria phage MS2
; genotoxicity
; priority journal
; waste water
; water quality
; California
; United States
英文摘要: Treatment of fully nitrified municipal wastewater effluents with chlorine followed by chloramines (i.e., sequential chlorine disinfection) upstream of advanced treatment trains can contribute pathogen inactivation credits for potable reuse while leaving a chloramine residual to control biofouling on membrane units in the advanced treatment train. However, free chlorine exposures must be optimized to maximize pathogen inactivation while minimizing the formation of disinfection byproducts (DBPs) that are challenging to remove in the advanced treatment train. Using a pilot-scale disinfection contactor receiving fully-nitrified, tertiary municipal wastewater effluent, this study found that a 3 mg × min/L free chlorine CT (i.e., the product of the chlorine residual “C” and the contact time “T”) followed by a 140 mg × min/L chloramine CT could reliably achieve 5-log inactivation of MS2 bacteriophage and reduce median total coliform concentrations below 2.2 MPN/100 mL. Free chlorine disinfection was equally effective when chlorine was dosed to exceed the breakpoint for 1 mg/L of ammonia as N. At this free chlorine exposure, regulated trihalomethane (THM) and haloacetic acid (HAA) formation remained below their Maximum Contaminant Levels (MCLs), but NDMA concentrations of ∼30 ng/L were above the 10 ng/L California Notification Level. Increasing the free chlorine exposure to ∼30 mg × min/L increased THM and HAA formation, with regulated THMs approaching or exceeding the MCL. Although this free chlorine exposure prevented NDMA formation during chloramination, the ∼10 ng/L background NDMA formation in the tertiary effluent remained. Increasing the free chlorine exposure also increased the formation of unregulated halogenated DBP classes that may be significant contributors to the DBP-associated toxicity of the disinfected wastewater. The results indicate that sequential chlorination can be used to optimize the benefits of free chlorine (virus and NDMA control) and chloramine disinfection (THM, HAA, and coliform control). © 2018 Elsevier Ltd Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/112566
Appears in Collections: 气候减缓与适应
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作者单位: Department of Civil and Environmental Engineering, Stanford University, 473 Via Ortega, Stanford, CA 94305, United States; Trussell Technologies, Inc., 1939 Harrison St., Suite 600, Oakland, CA 94612, United States
Recommended Citation:
Furst K.E.,Pecson B.M.,Webber B.D.,et al. Tradeoffs between pathogen inactivation and disinfection byproduct formation during sequential chlorine and chloramine disinfection for wastewater reuse[J]. Water Research,2018-01-01,143