DOI: 10.1029/2018JC014068
Scopus记录号: 2-s2.0-85052639976
论文题名: Zinc Geochemical Cycling in a Phosphorus-Rich Ocean During the Early Ediacaran
作者: Fan H. ; Wen H. ; Xiao C. ; Zhou T. ; Cloquet C. ; Zhu X.
刊名: Journal of Geophysical Research: Oceans
ISSN: 21699275
出版年: 2018
卷: 123, 期: 8 起始页码: 5248
结束页码: 5260
语种: 英语
英文关键词: early Ediacaran
; phosphorus-rich ocean
; south China
; zinc geochemical cycling
; Zn isotopes
Scopus关键词: Eukaryota
英文摘要: During the early Ediacaran, there was a large influx of phosphorus into the oceans and a resultant high phosphorus concentration in seawater, where multicellular eukaryotes may have been the primary type of marine productivity. The eukaryotes could play a critical role in regulating Zn cycling and isotopes. To establish Zn geochemical cycling patterns in the phosphorus-rich ocean, this study investigates Zn isotopic signatures of shallow water phosphorite that contains phosphatized microfossils (Weng'an biota) and deep-water shale from the Doushantuo Formation. Our results indicate that phosphorite commonly preserves heavier Zn isotope composition, with an average of 0.80‰. The positive δ66Zn values in phosphorites may be ascribed to Zn isotope fractionation associated with the complexation of Zn with phosphate and the adsorption of isotopically heavy Zn onto Fe-Mn oxides and organism's surfaces. We argue that phosphorite may represent an important sink of isotopically heavy Zn in a phosphorus-rich ocean during Earth history. Meanwhile, deep-water organic-rich shale shows an enrichment of isotopically light Zn with an average of 0.23‰, which may be attributed to sulfide precipitation in mid-depth environment. The organic-rich shale may represent an isotopically light Zn sink. In addition, the highest δ66Zn value (0.45‰) in a euxinic black shale may indicate that Zn isotope signal of anoxic deep water is similar to that of modern deep seawater. If that is the case, it suggests that Zn geochemical cycling in the early Ediacaran oceans was similar to that of modern oceans. ©2018. American Geophysical Union. All Rights Reserved. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/113355
Appears in Collections: 气候减缓与适应
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作者单位: State key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, China; College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing, China; Centre de Recherches Petrographiques et Geochimiques, Vandoeuvre-les-Nancy Cedex, France; MNR Key Laboratory of Isotope Geology, Institute of Geology, Chinese Academy of Geological Sciences, Beijing, China
Recommended Citation:
Fan H.,Wen H.,Xiao C.,et al. Zinc Geochemical Cycling in a Phosphorus-Rich Ocean During the Early Ediacaran[J]. Journal of Geophysical Research: Oceans,2018-01-01,123(8)