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This work presents a study of a magnesium/air combustion process in the context of innovative zero carbon dioxide (CO2) energy carriers for reducing global warming effects. In order to analyze more deeply the confined combustion of magnesium under fluctuating overpressure conditions (0 to 24 hPa) and the generated gaseous by-products, magnesium/air flames have been realized in a combustion chamber with a conical bluff-body as flame holder and different contraction ratios diaphragms at the exit duct. Sieved magnesium samples with two size-fractions were tested: 20-50 mu m and 50-70 mu m. The gaseous emissions of nitrogen oxides (NOx) and dioxygen (O-2) were analyzed with on-line infrared, ultraviolet and paramagnetic analyzers. A flame pulsating behavior was clearly observed from light emission intensity (monitored by a photodiode) and pressure fluctuations (monitored by a pressure sensor); the frequencies obtained ranged between 3 and 10 Hz. The frequency of the pulsation exhibited strong dependence on the geometric configuration of the chamber a contraction diaphragm divided by two the frequency level of the fluctuations in the studied range of maximum overpressure. Such fluctuations may probably be the consequence of periodic perturbations of the recirculation zone behind the bluff-body. These periodic perturbations are themselves caused by strong periodic overpressure variations due to stiff contraction downstream responding to gas velocity fluctuations. This feed-back-loop mechanism was considered in this study. NOx emissions produced through the thermal pathway were analyzed for equivalence ratios ranging from 0.29 to 1. The representation of NOx versus equivalence ratio exhibited a parabolic shape with a maximum for an equivalence ratio of 0.4. Moreover, NOx emissions of this metal combustor have shown a similar order of magnitude than current internal combustion engines. (C) 2018 The Combustion Institute. Published by Elsevier Inc. All rights reserved.