globalchange  > 气候减缓与适应
DOI: 10.1002/chem.201805264
WOS记录号: WOS:000454705500016
论文题名:
On the Theory of Electrolytic Dissociation, the Greenhouse Effect, and Activation Energy in (Electro)Catalysis: A Tribute to Svante Augustus Arrhenius
作者: Masa, Justus; Barwe, Stefan; Andronescu, Corina; Schuhmann, Wolfgang
通讯作者: Masa, Justus ; Schuhmann, Wolfgang
刊名: CHEMISTRY-A EUROPEAN JOURNAL
ISSN: 0947-6539
EISSN: 1521-3765
出版年: 2019
卷: 25, 期:1, 页码:158-166
语种: 英语
英文关键词: activation energy ; electrocatalysis ; electrolytic dissociation ; Nobel prize in chemistry 1903 ; Svante August Arrhenius
WOS关键词: QUANTUM ; CHEMISTRY ; HYDRATION ; PLOTS
WOS学科分类: Chemistry, Multidisciplinary
WOS研究方向: Chemistry
英文摘要:

There are powerful lessons to take from Svante August Arrhenius' journey leading to a Nobel laureate as there are from his tremendous contributions to chemistry and science in general, including climate science, immunochemistry and cosmology. The theory of electrolytic dissociation for which Arrhenius received the 1903 Nobel Prize in Chemistry has had a profound impact on our understanding of the chemistry of solutions, chemical reactivity, mechanisms underlying chemical transformations as well as physiological processes. As a tribute to Arrhenius, we present a brief historical perspective and present status of the theory of electrolytic dissociation, its relevance and role to the development of electrochemistry, as well as some perspectives on the possible role of the theory to future advancements in electroanalysis, electrocatalysis and electrochemical energy storage. The review briefly highlights Arrhenius' contribution to climate science owing to his studies on the potential effects of increased anthropogenic CO2 emissions on the global climate. These studies were far ahead of their time and revealed a daunting global dilemma, global warming, that we are faced with today. Efforts to abate or reverse CO2 accumulation constitute one of the most pressing scientific problems of our time, "man's urgent strive to save self from the adverse effects of his self-orchestrated change on the climate". Finally, we review the application of the Arrhenius equation that correlates reaction rate constants (k) and temperature (T); k=Ae(-Ea/RT), in determining reaction barriers in catalysis with a particular focus on recent modifications of the equation to account for reactions exhibiting non-linear Arrhenius behavior with concave curvature due to prevalence of quantum mechanical tunneling, as well as infrequent convexity of Arrhenius plots due to decrease of the microcanonical rate coefficient with energy as observed for some enzyme catalyzed reactions.


Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/127633
Appears in Collections:气候减缓与适应

Files in This Item:

There are no files associated with this item.


作者单位: Ruhr Univ Bochum, Analyt Chem, CES, Fac Chem & Biochem, Univ Str 150, D-44780 Bochum, Germany

Recommended Citation:
Masa, Justus,Barwe, Stefan,Andronescu, Corina,et al. On the Theory of Electrolytic Dissociation, the Greenhouse Effect, and Activation Energy in (Electro)Catalysis: A Tribute to Svante Augustus Arrhenius[J]. CHEMISTRY-A EUROPEAN JOURNAL,2019-01-01,25(1):158-166
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Masa, Justus]'s Articles
[Barwe, Stefan]'s Articles
[Andronescu, Corina]'s Articles
百度学术
Similar articles in Baidu Scholar
[Masa, Justus]'s Articles
[Barwe, Stefan]'s Articles
[Andronescu, Corina]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Masa, Justus]‘s Articles
[Barwe, Stefan]‘s Articles
[Andronescu, Corina]‘s Articles
Related Copyright Policies
Null
收藏/分享
所有评论 (0)
暂无评论
 

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.