globalchange  > 气候减缓与适应
DOI: 10.5194/acp-19-447-2019
WOS记录号: WOS:000455810000002
论文题名:
Characterization of black carbon-containing fine particles in Beijing during wintertime
作者: Wang, Junfeng1; Liu, Dantong2; Ge, Xinlei1; Wu, Yangzhou1; Shen, Fuzhen1; Chen, Mindong1; Zhao, Jian3,4; Xie, Conghui3,4; Wang, Qingqing3; Xu, Weiqi3,4; Zhang, Jie5; Hu, Jianlin1; Allan, James2,6; Joshi, Rutambhara2; Fu, Pingqing3; Coe, Hugh2; Sun, Yele4
通讯作者: Ge, Xinlei
刊名: ATMOSPHERIC CHEMISTRY AND PHYSICS
ISSN: 1680-7316
EISSN: 1680-7324
出版年: 2019
卷: 19, 期:1, 页码:447-458
语种: 英语
WOS关键词: AEROSOL MASS-SPECTROMETER ; POSITIVE MATRIX FACTORIZATION ; ORGANIC AEROSOL ; MIXING STATE ; ABSORPTION ENHANCEMENT ; LIGHT-ABSORPTION ; AQUEOUS-PHASE ; BROWN CARBON ; REGIONAL TRANSPORT ; HAZE POLLUTION
WOS学科分类: Environmental Sciences ; Meteorology & Atmospheric Sciences
WOS研究方向: Environmental Sciences & Ecology ; Meteorology & Atmospheric Sciences
英文摘要:

Refractory black carbon (BC) is a product of incomplete combustion of fossil fuel, biomass and biofuel, etc. By mixing with other species, BC can play significant roles in climate change, visibility impairment and human health. Such BC-containing particles in densely populated megacities like Beijing may have specific sources and properties that are important to haze formation and air quality. In this work, we exclusively characterized the BC-containing particles in urban Beijing by using a laser-only Aerodyne soot particle aerosol mass spectrometer (SP-AMS), as part of the Atmospheric Pollution & Human Health (APHH) 2016 winter campaign. The average mass ratio of coating to BC core (R-BC) was found to be similar to 5.0. Positive matrix factorization shows the presence of significant primary fossil fuel and biomass-burning organics (64% of total organics). Yet secondary species, including sulfate, nitrate and oxygenated organic aerosol (OA) species, could have significant impacts on the properties of BC-containing particles, especially for ones with larger BC core sizes and thicker coatings. Analyses of sources and diurnal cycles of organic coating reveal significant afternoon photochemical production of secondary OA (SOA), as well as nighttime aqueous production of a portion of highly oxygenated OA. Besides SOA, photochemical production of nitrate, not sulfate, appeared to be important. Further investigations on BC-containing particles during different periods show that, on average, more polluted periods would have more contributions from secondary species and more thickly coated BC tended to associate with more secondary species, indicating the important role of chemical aging to the pollution of BC-containing particles in urban Beijing during wintertime. However, for individual pollution events, primary species (fossil fuel, coal and biomass-burning emissions) could also play a dominant role, as revealed by the compositions of BC-containing particles in two polluted episodes during the sampling period.


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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/127868
Appears in Collections:气候减缓与适应

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作者单位: 1.Nanjing Univ Informat Sci & Technol, Sch Environm Sci & Engn, Collaborat Innovat Ctr Atmospher Environm & Equip, Jiangsu Key Lab Atmospher Environm Monitoring & P, Nanjing 210044, Jiangsu, Peoples R China
2.Univ Manchester, Sch Earth & Environm Sci, Manchester M13 9PL, Lancs, England
3.Chinese Acad Sci, Inst Atmospher Phys, State Key Lab Atmospher Boundary Layer Phys & Atm, Beijing 100029, Peoples R China
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
5.SUNY Albany, Atmospher Sci Res Ctr, Albany, NY 12203 USA
6.Univ Manchester, Natl Ctr Atmospher Sci, Manchester M13 9PL, Lancs, England

Recommended Citation:
Wang, Junfeng,Liu, Dantong,Ge, Xinlei,et al. Characterization of black carbon-containing fine particles in Beijing during wintertime[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2019-01-01,19(1):447-458
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