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Soil hydrological properties not only directly influenced soil water content, evapotranspiration, infiltration, and runoff, but also made these factors of concern in arid and semi-arid regions. Prior research has focused on the temporal and spatial variation in soil hydrological properties and the impacts of climate change, ecosystem changes over time or human activities on soil hydrological properties. However, studies conducted on the differences in soil hydrological properties between shady and sunny slopes have seldom been conducted, especially in the permafrost region of the Qinghai-Tibetan Plateau. To investigate the variation in soil hydrological properties on shady and sunny slopes, we chose the Zuomaokongqu watershed of Fenghuo Mountain, which is located on the Qinghai-Tibetan Plateau, as the study area. Three experimental sites were selected in the study area, and the distance between experimental sites was 100m. Based on the differences in altitude and vegetation coverage, five sunny slope sample points and three shady slope sample points were selected in each experimental site. At each of these sample points, the soil water content, soil-saturated conductivity, soil water-retention curve, soil physico-chemical properties, aboveground biomass, and underground biomass were examined in the top 0-50cm of the active layer. The results showed that the soil hydrological properties of shady slopes differed significantly from those of sunny slopes. The soil water content of sunny slopes was 20.9% less than that of shady slopes. The soil-saturated water content of sunny slopes was 12.2% less than that of shady slopes. The soil water content of sunny slopes at -0.3Mpa and -0.7Mpa matric potential was 23.5% and 21.4% less than that of shady slopes, respectively. It was indicated that the soil water-retention capacity of sunny slopes was lower than that of shady slopes. However, the soil-saturated conductivity of sunny slopes was 84.5% larger than that of shady slopes and exceeded the range of soil-saturated conductivity, which was useful for plant growth. Meanwhile, the vegetation coverage on sunny slopes was lower than that on shady slopes, but the soil sand content showed the opposite relationship. Pearson's coefficient analysis results showed that vegetation coverage and soil desertification, which are affected by permafrost degradation, were the main factors influencing soil hydrological properties on shady and sunny slopes. These results will help determine appropriate hydraulic parameters for hydrological models in mountain areas.