globalchange  > 气候减缓与适应
DOI: 10.1002/etc.4333
WOS记录号: WOS:000457470000008
论文题名:
Environmental conditions affecting re-release from particulate matter of 4-Nonylphenol into an aqueous medium
作者: Lyons, Rebecca; Togashi, Trevor; Bowyer, Chad
通讯作者: Lyons, Rebecca
刊名: ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY
ISSN: 0730-7268
EISSN: 1552-8618
出版年: 2019
卷: 38, 期:2, 页码:350-360
语种: 英语
英文关键词: Endocrine disruptors ; Desorption ; Climate change ; Particulates ; Environmental reservoirs
WOS关键词: SOIL ORGANIC-MATTER ; SIERRA-NEVADA ; BLACK CARBON ; SORPTION ; NONYLPHENOL ; POLLUTANTS ; DESORPTION ; CALIFORNIA ; TRANSPORT ; WATER
WOS学科分类: Environmental Sciences ; Toxicology
WOS研究方向: Environmental Sciences & Ecology ; Toxicology
英文摘要:

4-nonylphenol is a persistent organic pollutant with endocrine-disrupting properties. A nonpolar product of microbial degradation derived from the surfactant nonylphenol polyethoxylate, 4-nonylphenol is capable of long-range transport attached to particulates. Bioactive concentrations of 4-nonylphenol have been found in the surface water, soils, snow, and particulate matter of the Eastern Sierra Nevada Mountains (USA) hundreds of miles from their origins. As a result of particulate deposition, seasonal and glacial snow pack concentrations measured 20 to 100 times higher than in surface waters. Batch desorption assays were run on particulate matter dosed with 4-nonylphenol. Desorption was measured in 63 to 500 mu m particles under 2 different temperature conditions with varying fractions of organic carbon in turbulent or undisturbed states. Lower temperatures (4 degrees C) decreased the mean percentage of 4-nonylphenol released from particulates in disturbed and undisturbed conditions, whereas the mean percentage of 4-nonylphenol released at 20 degrees C was reduced by agitation. The effect of agitation at 4 degrees C was not practically or statistically significant. Particulates with a higher percentage of organic carbon (75%) released very little of the bound 4-nonylphenol (0.53%) compared with particulates containing 4 to 5% of organic carbon that released up to 13%. Larger particles released the least amount of 4-nonylphenol, whereas smaller particles released the most amount. Water and sediment samples taken from below the Palisades Glacier in the Sierra Nevada Mountains showed the greatest 4-nonylphenol concentrations directly below the glacier, implying that glacial particulates will release adsorbed 4-nonylphenol. Environ Toxicol Chem 2019;38:350-360. (c) 2018 SETAC


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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/129340
Appears in Collections:气候减缓与适应

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作者单位: Univ Redlands, Coll Arts & Sci Chem, Redlands, CA 92373 USA

Recommended Citation:
Lyons, Rebecca,Togashi, Trevor,Bowyer, Chad. Environmental conditions affecting re-release from particulate matter of 4-Nonylphenol into an aqueous medium[J]. ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY,2019-01-01,38(2):350-360
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