Elemental data from travertines are a treasure of depositional and diagenetic information. However, correct interpretation requires proper data acquisition and treatment. This study shows how results from elemental analyses complement sedimentological and other geochemical, i.e. isotopic, data and thereby contribute to our understanding of fossil travertines. Multivariate statistical element analyses, after multiple travertine digestion methods, demonstrate the link between elements, their mineralogical phases, and ultimately their origin. This study reveals that carbonate-phase related elements in travertines (Sr, S, Ba, Mg and Na) originate dominantly from the fluid source rocks. In combination with the delta O-18 and delta C-13 signatures, they are thus key geochemical variables for comparison of different travertine geobodies. Geochemical data analysis (elemental concentrations and isotope signatures), as illustrated here for the Turkish Battik travertines, supports interpretation with regard to fluid source rock, distance from the vent and relative intensity of processes like evaporation and degassing. For fossil travertines, geochemical data can thus provide crucial insights for understanding the hydrologic system. In particular when information is restricted to borehole data, like in subsurface reservoirs, their application could be decisive. (C) 2019 Elsevier B.V. All rights reserved.
1.Katholieke Univ Leuven, Geodynam & Geofluids Res Grp, Dept Earth & Environm Sci, Celestijnenlaan 200E, B-3001 Leuven, Belgium 2.Rhein Westfal TH Aachen, CIM, Bunsenstr 8, D-52072 Aachen, Germany 3.Vrije Univ Brussel, Hydrol & Hydraul Engn, Pl Laan 2, B-1050 Brussels, Belgium 4.Flemish Inst Technol Res, VITO, Boeretang 200, B-2400 Mol, Belgium 5.Petrobras Res Ctr, Av Horacio de Macedo Cidade Univ 950, BR-21941915 Rio De Janeiro, RJ, Brazil 6.SCR Sibelco Nv, Dept Geol, Zate 1, BE-2480 Dessel, Belgium 7.Pamukkale Univ, Dept Geol Engn, Kinikh Campus, TR-20070 Denizli, Turkey
Recommended Citation:
Claes, Hannes,Huysmans, Marijke,Soete, Jeroen,et al. Elemental geochemistry to complement stable isotope data of fossil travertine: Importance of digestion method and statistics[J]. SEDIMENTARY GEOLOGY,2019-01-01,386:118-131