globalchange  > 过去全球变化的重建
DOI: 10.1016/j.envres.2019.04.020
WOS记录号: WOS:000470801100009
论文题名:
Performance of dry water- and porous carbon-based sorbents for carbon dioxide capture
作者: Al-Wabel, Mohammad1; Elfaki, Jamal1,2; Usman, Adel1,3; Hussain, Qaiser1,4; Ok, Yong Sik5
通讯作者: Al-Wabel, Mohammad
刊名: ENVIRONMENTAL RESEARCH
ISSN: 0013-9351
EISSN: 1096-0953
出版年: 2019
卷: 174, 页码:69-79
语种: 英语
英文关键词: Dry water ; Activated carbon ; Partition coefficient ; Gas adsorbent ; Biochar ; CO2 adsorption
WOS关键词: ACTIVATED CARBON ; CO2 ADSORPTION ; FLUE-GAS ; STABILITY ; BIOCHAR ; SEPARATION ; ADSORBENT ; ZEOLITES ; STORAGE ; SHELL
WOS学科分类: Environmental Sciences ; Public, Environmental & Occupational Health
WOS研究方向: Environmental Sciences & Ecology ; Public, Environmental & Occupational Health
英文摘要:

Carbon dioxide is the primary greenhouse gas that has a strong impact on global warming. Several technologies have been developed for capturing CO2 to mitigate the greenhouse effect. The objective of this research was to investigate the performance of several sorbents based on dry water and porous carbon materials for capturing CO2. Seven sorbents were prepared and comparatively evaluated for their CO2 capture capabilities: (i) Conocarpus biochar (CBC); (ii) commercial activated carbon (CAC); (iii) normal dry water (NDW); (iv) K2CO3-treated CBC (TCBC); (v) K2CO3-modified dry water (MDW); (vi) MDW and 2% TCBC (MDWTCBC); and (vii) MDW and 2% activated carbon (MDWCAC). The sorption process was carried out with initial CO2 concentration of 5.7%, temperature of 25 degrees C, feed gas flow rate of 0.51 min(-1) and a pressure of 1.0 bar. The pure CO2 was mixed with O-2 or N-2 to achieve the desired inlet concentration of CO2. The CO2 adsorption capacity and partition coefficient (PC) of the tested sorbents were evaluated at 5% and 100% breakthrough (BT). The results showed a longer breakthrough and equilibrium adsorption times for CO2 when mixed with N-2 than with O-2. Among all sorbents, both CAC and CBC showed enhanced CO2 capture performance with equilibrium (100% BT) adsorption capacities of 239 and 197 mg g(-1), respectively (in terms of PC: 1.0 x 10(-3) and 7.9 x 10(-4) mol kg(-1) Pa-1, respectively). In contrast, the performance of TCBC and the dry water-based sorbents was far lower than CAC or CBC. The CO2 adsorption data fitted well to the non-linearized form of the pseudo-first-order kinetic model. The Fourier-transform infrared spectral patterns indicated that the reaction of CO2 molecules with the hydroxyl groups of sorbents is possible through the formation of chemisorbed CO2 species. It could be concluded that the activation process did not play a role in increasing the CO2 capture performance in order to form new active sorption sites. However, Conocarpus biochar can be used as efficient sorbent for CO2 capture with a better performance than other materials tested previously (e.g., activated carbon).


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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/141172
Appears in Collections:过去全球变化的重建

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作者单位: 1.King Saud Univ, Coll Food & Agr Sci, Soil Sci Dept, POB 2460, Riyadh 11451, Saudi Arabia
2.Nile Valley Univ, Fac Agr, Khartoum, River Nile Stat, Sudan
3.Assiut Univ, Fac Agr, Dept Soils & Water, Assiut 71526, Egypt
4.Pir Mehr All Shah Arid Agr Univ, Inst Soil Sci, Rawalpindi 46300, Punjab, Pakistan
5.Korea Univ, Div Environm Sci & Ecol Engn, OJERI, Korea Biochar Res Ctr, Seoul 02841, South Korea

Recommended Citation:
Al-Wabel, Mohammad,Elfaki, Jamal,Usman, Adel,et al. Performance of dry water- and porous carbon-based sorbents for carbon dioxide capture[J]. ENVIRONMENTAL RESEARCH,2019-01-01,174:69-79
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