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Volcanism provides a reliable record of local and global tectonic events and substantially influences both modern and ancient environments, climates, and the evolution of life. The Ordovician-Silurian (O-S) transition is a special period because intensive volcanism occurred globally, including in the Yangtze region of South China. Volcanic events during this period are a symptom of plate tectonic behaviour and are thought to be responsible for the remarkable changes in climate in the early Palaeozoic, though the relationships between these events remain unclear and controversial. Coeval igneous rocks and volcanic sediments (VS) are primarily used to resolve this issue. However, limited studies have been performed on VS from the O-S transition in South China. Recently, a typical VS-bearing section was found in the Lower Yangtze region, which contains similar to 100 thin, interbedded volcanic ash layers across the O-S transition. Detailed petrographic and geochemical analyses of the volcanic ashes were conducted to determine their isotopic ages, magma sources, evolutionary processes, and tectonic settings. Our preliminary results suggest that volcanic eruptions in South China lasted for more than 22 Ma across the O-S boundary, from similar to 449.3 +/- 3.6 to 427.6 +/- 4.1 Ma, where 445.14 Ma is the lowermost graptolite biozone for Metabolograptus extraordinarius, as well as the initiation of the Late Ordovician mass extinction (LOME) event in the Yangtze region. The evolutionary history of the parental magma was constructed from a depleted mantle source in the early stage and from a crustal source in the late stage, with several transitional features in the middle. The mantle source and arc-related geochemical indicators for the volcanic ashes support the disputed "subduction-collision orogeny" model. We propose that the strong volcanism in South China, accompanied by volcanism in numerous other regions worldwide, was an important trigger for the LOME and was likely responsible for oceanic Sr-87/Sr-86 fractionation and other climatic changes during the O-S transition. (C) 2019 Elsevier B.V. All rights reserved.