CARBONATE-ASSOCIATED SULFATE
; HIGH-RESOLUTION BIOCHRONOLOGY
; SMITHIAN-SPATHIAN BOUNDARY
; REDUCED INORGANIC SULFUR
; LARGE IGNEOUS PROVINCES
; OCEANIC ANOXIC EVENTS
; SR ISOTOPE VARIATIONS
; SEAWATER SULFATE
; OXYGEN ISOTOPES
; SOUTH CHINA
WOS学科分类:
Geosciences, Multidisciplinary
WOS研究方向:
Geology
英文摘要:
Perturbations to the global carbon and sulfur cycles recurred episodically throughout the similar to 5-Myr-long Early Triassic, in the aftermath of the end-Permian mass extinction, the largest biocrisis in Earth's history. In this study, analyses of carbonate-associated sulfate (CAS) sulfur, CAS oxygen, and pyrite sulfur-isotope ratios in a continental shelf section from the southern Neo-Tethys Ocean (Spiti Valley, India) provide new insights into the Early Triassic marine sulfur cycle. Secular variation in CAS sulfur-isotope values at Spiti is similar to that in South China, suggesting that CAS was a robust recorder of a global seawater sulfate signal. The Spiti CAS and pyrite delta S-34 profiles show that the highest rates of pyrite burial coincided with cooler sea-surface temperatures. We infer that climatic cooling steepened equator-to-pole temperature gradients, invigorating thermohaline overturning circulation, and enhancing upwelling of nutrients that stimulated marine productivity and organic carbon sinking fluxes. Enhanced productivity fueled and sustained microbial respiration, increased oxygen demand, and, within the southern Neo-Tethys, caused the zone of microbial sulfate reduction to migrate upwards and become more connected to the water column. Microbial sulfate reduction, under these conditions, was no longer limited by organic matter or sulfate availability, leading to burial of more S-34-depleted pyrite and S-34- and O-18-enrichment of the oceanic sulfate pool. This environmental scenario suggests possible environmental stresses related to eutrophication during positive carbon-isotope excursions around the Griesbachian-Dienerian, Dienerian-Smithian, and Smithian-Spathian boundaries. Additionally, the difference between CAS and pyrite sulfur-isotope values, Delta S-34(CAS-pyr), slowly rose through the Early Triassic, reflecting a slow increase in seawater sulfate concentrations following a minimum close to the Permian-Triassic boundary.
1.Univ Massachusetts, Sch Environm, Boston, MA 02125 USA 2.Univ Cincinnati, Dept Geol, Cincinnati, OH 45221 USA 3.China Univ Geosci, State Key Labs BGEG & GPMR, Wuhan 430074, Hubei, Peoples R China 4.Univ Vienna, Inst Paleontol, Althanstr 14, A-1090 Vienna, Austria 5.Univ Texas Austin, Bur Econ Geol, Austin, TX 78758 USA 6.Kent State Univ, Dept Geol, Kent, OH 44242 USA
Recommended Citation:
Stebbins, Alan,Algeo, Thomas J.,Krystyn, Leopold,et al. Marine sulfur cycle evidence for upwelling and eutrophic stresses during Early Triassic cooling events[J]. EARTH-SCIENCE REVIEWS,2019-01-01,195:68-82