globalchange  > 全球变化的国际研究计划
DOI: 10.1016/j.molliq.2019.111064
WOS记录号: WOS:000480664700056
论文题名:
Carbon dioxide solubility in the aqueous mixtures of diisopropanolamine plus L-arginine and diethanolamine plus L-arginine at high pressures
作者: Haghtalab, Ali; Gholami, Valiolah
通讯作者: Haghtalab, Ali
刊名: JOURNAL OF MOLECULAR LIQUIDS
ISSN: 0167-7322
EISSN: 1873-3166
出版年: 2019
卷: 288
语种: 英语
英文关键词: Solubility ; CO2 ; Alkanolamine ; Amino acid ; Arginine ; DIPA ; DEA
WOS关键词: VAPOR-LIQUID-EQUILIBRIA ; AMINO-ACID SALTS ; IONIC LIQUID ; HYDROGEN-SULFIDE ; DISSOCIATION-CONSTANTS ; CO2 ; ABSORPTION ; CAPTURE ; DENSITY ; ALKANOLAMINES
WOS学科分类: Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS研究方向: Chemistry ; Physics
英文摘要:

In recent years, emission of greenhouse gases especially carbon dioxide has been increased so that CO2 is accounted for as a gas pollutant and leads to global warming. Thus, the removal of carbon dioxide is an important step in a gas capturing process. The absorption of CO2 in a mixture of alkanolamine + amino acid is a promising technique since this mixture reduces disposable contaminated solvents. In this work, CO2 solubility is measured in the aqueous solution of diisopropanolamine (DIPA) + L-arginine (ARG) and diethanolamine (DEA) + L-arginine (ARG) systems using a static high-pressure cell. We carried out the measurements at total pressure range of 1-38 bars and under isothermal conditions of 328.15, 348.15 and 363.15 K. We kept the total amine (amine + amino acid) concentration in the solution at 40 wt%, since this concentration has been shown that to be more effective in capturing of CO2 in a gas treatment industry. The compositions of the different systems were used as DIPA (40 wt%), DIPA + ARG (35 + 5 wt%), DIPA + ARG (30 + 10 wt%), DIPA + ARG (25 + 15 wt%), DEA (40 wt%), DEA + ARG (35 + 5 wt%), and DEA + ARG (30 + 10 wt%). We measured and correlated the densities of all mixtures versus temperature and mass fractions of the alkanolamine +amino acid. We presented the results as the partial pressure of CO2 against its gas loading. It was found that loading of CO2 enhanced with increasing pressure or decreasing temperature. Moreover, ARG (10 wt%) can mostly affect the CO2 solubility in DIPA + ARG and DEA + ARG systems at high temperature. Furthermore, a quadratic equation was used for correlation of the partial pressure of CO2 against the gas loading so that the calculated results showed a good agreement with the experiment Finally, the Clausius-Clapeyron equation was used for computation of the enthalpy of CO2 absorption for the present systems. As a result, it was shown that the DIPA + ARC (35 + 5 wt%) and DEA + ARG (35 + 5 wt%) systems have the lowest enthalpy of CO2 absorption (Delta H-abs) values, respectively, so that these systems require less energy in a regeneration unit. (C) 2019 Elsevier B.V. All rights reserved.


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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/145489
Appears in Collections:全球变化的国际研究计划

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作者单位: Tarbiat Modares Univ, Dept Chem Engn, POB 14115-143, Tehran, Iran

Recommended Citation:
Haghtalab, Ali,Gholami, Valiolah. Carbon dioxide solubility in the aqueous mixtures of diisopropanolamine plus L-arginine and diethanolamine plus L-arginine at high pressures[J]. JOURNAL OF MOLECULAR LIQUIDS,2019-01-01,288
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