globalchange  > 气候变化与战略
CSCD记录号: CSCD:5236695
论文题名:
崇明岛湿地沉积物中六六六的长期变化趋势
其他题名: Long-term Variation Trend of HCHs in the Sediment Core of Chongming Island Wetland
作者: 朱晓华1; 潘静1; 路国慧1; 陈大舟2; 汤桦2; 王卓1; 刘晓端1; 杨永亮1
刊名: 地球与环境
ISSN: 1672-9250
出版年: 2014
卷: 42, 期:4
语种: 中文
中文关键词: 有机氯农药 ; 同位素稀释质谱法 ; 柱状沉积物 ; 东滩湿地
英文关键词: organochlorine pesticide ; IDMS ; sediment core ; Dongtan Wetland
WOS学科分类: ENVIRONMENTAL SCIENCES
WOS研究方向: Environmental Sciences & Ecology
中文摘要: 采用同位素稀释质谱法,利用高分辨率气相色谱-高分辨率质谱法(HRGC-HRMS)分析测定了崇明岛东滩柱状沉积物样品的30个层段中HCHs的含量,对其垂直分布特征进行了初步探讨。沉积物中HCHs均被检出。东滩湿地沉积物中总HCHs含量范围为0.35~0.98ng·g~(-1)dw,平均值为0.64ng·g~(-1)dw,属于轻度污染。HCHs呈现明显的周期性变化。采用时间序列分析方法,统计分析了近60年来东滩湿地沉积物中HCHs变化的总体趋势与主要振荡周期。长期变化趋势表明东滩沉积物中HCHs在上世纪50年代初开始增长,高峰期出现在上世纪60至70年代。一些异构体在我国停止生产HCHs后,没有明显的下降趋势。频谱分析结果表明HCHs的分布表现出具有周期为大约8年的振荡特征,可能与气候变化周期相关。
英文摘要: The concentrations of hexachlorocyclohexanes(HCHs)in the sediment cores taken from the Dongtan Wetland at the Yangtze River Estuary of the East China Sea were measured by isotope dilution mass spectrometry (IDMS)with HRGCHRMS. The vertical distribution characteristics of HCHs concentrations with depth and possible influence by climate changes were preliminarily discussed.HCHs were found in all sediment layers.The total HCHs concentrations range from 0.35to 0. 98ng·g~(-1)dw with the average of 0.64ng·g~(-1)dw for the Dongtan Wetland,showing a low pollution level.The vertical distributions of HCHs isomers in the cores showed significant periodic variations.By time-series analysis,the long-term variation trends and frequency spectra of HCHs in the sediment cores of the Dongtan Wetland during the last 60years were discussed. The long-term variation trends of HCHs in the wetland showed that these chemicals began to rise in the early 1950swith the maxima during the 1960s~1970s.Some isomers did not show significant declining trends after their productions were banned. The time-series generally show an 8-year periodicity,suggesting an influence of ENSO.
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/147636
Appears in Collections:气候变化与战略

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作者单位: 1.国家地质实验测试中心, 国土资源部生态地球化学开放实验室, 北京 100037, 中国
2.中国计量科学研究院化学计量与分析科学研究所, 北京 100013, 中国

Recommended Citation:
朱晓华,潘静,路国慧,等. 崇明岛湿地沉积物中六六六的长期变化趋势[J]. 地球与环境,2014-01-01,42(4)
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