globalchange  > 气候变化与战略
CSCD记录号: CSCD:5055667
论文题名:
三氟甲烷(HFC-23)的资源化转化利用
其他题名: Conversion and resource utilization of waste CHF_3 gas
作者: 韩文锋1; 靳碧波1; 周强2; 王树华2
刊名: 化工进展
ISSN: 1000-6613
出版年: 2014
卷: 33, 期:2, 页码:103-111
语种: 中文
中文关键词: 温室气体 ; 化学过程 ; 废物处理 ; 三氟甲烷 ; 资源化利用 ; 高温裂解
英文关键词: greenhouse gas ; chemical processes ; waste treatment ; trifluotomethane ; resource utilization ; pyrolysis
WOS学科分类: CHEMISTRY MULTIDISCIPLINARY ; CHEMISTRY ORGANIC ; CHEMISTRY PHYSICAL
WOS研究方向: Chemistry
中文摘要: 三氟甲烷(CHF_3)是一种强温室气体,其温室效应潜值是CO_2的14800倍,因此,CHF_3的处理是温室气体减排中一个十分重要和关键的课题。CHF_3的排放源相对集中,纯度较高,因此十分有利于对其进行资源化利用而非目前所采取的高温焚烧法。本文主要综述了有关CHF_3废气的资源化利用的研究现状,指出对其进行高温裂解(700℃以上),可以选择性地合成C_2F_4(TFE,四氟乙烯)和C_3F_6(HFP,六氟丙烯)。合适的催化剂可以显著提高CHF_3转化率及C_2F_4和C_3F_6的收率。CHF_3与CH_4反应可以高选择性地合成CH_2=CF_2(VDF,偏氟乙烯),具有一定的工业价值;其缺点是副产物较多。而利用CHF_3与I_2反应合成CF_3I,是另一条较有吸引力的工艺路线。CF_3I不仅可以作为灭火剂及制冷剂,而且作为三氟甲基化试剂也具有很大的市场空间。将CHF_3直接作为三氟甲基化试剂还处于实验室初步探索阶段,其过程条件较为苛刻及成本较高,将其作为CHF_3处理路线还有待长时间探索。
英文摘要: CHF_3 is a potent greenhouse gas with global warming potential of 14 800 times higher than that of CO_2. Therefore,it plays a very important and critical role in the reduction of greenhouse gas emission. As CHF_3 is produced with relatively high purity,it is very beneficial to realize resource utilization rather than high-temperature incineration which is currently used by industry. This review summarizes the research on the resource utilization of waste CHF_3 gas. Via high-temperature pyrolysis (>700℃),CHF_3 can be converted to C_2F_4 (TFE,tetrafluoroethylene) and C_3F_6 (HFP, hexafluoropropylene) selectively. The presence of a suitable catalyst can significantly improve the conversion of CHF_3 and the yields of C_2F_4 and C_3F_6. Reaction of CHF_3 with CH_4 leads to the formation of CH_2=CF_2 (VDF,vinylidene fluoride),making it an alternative route for the resource utilization of CHF_3. The major shortcoming of this route is its various by-products. CF_3I can be synthesized via reaction of CHF_3 with I_2 which is another attractive process. As a fire-extinguishing agent and refrigerant,the cost of CF_3I is relatively high compared with other substitutes. In addition,CF_3I is widely used as trifluoromethyl reagent. It is reported that CHF_3 can be directly used as trifluoromethyl reagent in the presence of complicated catalysts under harsh conditions and with high cost. This route is still under preliminary exploration in the laboratory and has a long way to commercial application.
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/147921
Appears in Collections:气候变化与战略

Files in This Item:

There are no files associated with this item.


作者单位: 1.浙江工业大学工业催化研究所, 杭州, 浙江 310014, 中国
2.巨化集团研究院, 衢州, 浙江 324004, 中国

Recommended Citation:
韩文锋,靳碧波,周强,等. 三氟甲烷(HFC-23)的资源化转化利用[J]. 化工进展,2014-01-01,33(2):103-111
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[韩文锋]'s Articles
[靳碧波]'s Articles
[周强]'s Articles
百度学术
Similar articles in Baidu Scholar
[韩文锋]'s Articles
[靳碧波]'s Articles
[周强]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[韩文锋]‘s Articles
[靳碧波]‘s Articles
[周强]‘s Articles
Related Copyright Policies
Null
收藏/分享
所有评论 (0)
暂无评论
 

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.