globalchange  > 气候变化与战略
CSCD记录号: CSCD:5096157
论文题名:
石笋矿物由文石转变为方解石后碳、氧同位素组成的变化
其他题名: Variation of Oxygen and Carbon Isotope Compositions in Transformation of Speleothem Primary Aragonite to Secondary Calcite
作者: 张海伟; 蔡演军; 安芷生; 秦世江
刊名: 矿物岩石地球化学通报
ISSN: 1007-2802
出版年: 2014
卷: 33, 期:1, 页码:105-117
语种: 中文
中文关键词: 石笋 ; 矿物转变 ; 文石 ; 方解石 ; 碳、氧同位素
英文关键词: stalagmite ; aragonite ; calcite ; recrystallize ; carbon and oxygen isotopes
WOS学科分类: GEOLOGY
WOS研究方向: Geology
中文摘要: 石笋矿物由文石转变为方解石,其碳、氧同位素组成如何变化的认识对于古环境研究具有重要意义。选取江西省神农宫洞石笋SN15进行研究,X衍射分析测试证明其主体部分的矿物组成为文石,部分位置文石转变为方解石。相同层位文石和转变方解石的碳、氧同位素组成分析结果表明,转变方解石与原生文石相比,delta~(13)C值几乎没有变化;而delta~(18)O值明显偏负,且不是系统性偏负,偏负范围为0.2~1.4。因此,原生文石记录的降水氧同位素组成在矿物转变时受到扰动,转变方解石的氧同位素组成信息不能用于高分辨率古气候与古环境研究;碳同位素组成虽然变化很小,使用时也需慎重。
英文摘要: Knowledge on the variations of oxygen and carbon isotope compositions in the transformation of speleothem primary aragonite to secondary calcite is the foundation of paleo-environmental studies using speleothem. A stalagmite SN15, which was collected from the Shennong Cave, Jiangxi Province, southeastern China, has been identified by XRD analyzing that its aragonite has partially inverted into calcite. The comparisons of carbon and oxygen isotopic data series between secondary calcite and corresponding primary aragonite within stalagmite SN15 indicate that the delta~(13)C datum of calcite have a quite similar range to those of the aragonite, whereas the delta~(18)O values of calcite are depleted about 0.2-1.4 at random. Our result suggests that the oxygen isotopic data of calcite can hardly be used to investigate the paleo-climatic changes with high-resolution. Carbon isotope composition of calcite seems to be inherited from the aragonite, but it should be cautious to use the carbon isotopic data in paleo-environmental studies because the mechanism of aragonite-to-calcite transformation has not been fully understood.
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/148003
Appears in Collections:气候变化与战略

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作者单位: 中国科学院地球环境研究所, 黄土与第四纪地质国家重点实验室, 西安, 陕西 710075, 中国

Recommended Citation:
张海伟,蔡演军,安芷生,等. 石笋矿物由文石转变为方解石后碳、氧同位素组成的变化[J]. 矿物岩石地球化学通报,2014-01-01,33(1):105-117
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