globalchange  > 气候变化与战略
CSCD记录号: CSCD:5584872
论文题名:
Ag/Ag_2WO_4等离子体共振催化剂可见光催化还原CO_2
其他题名: Ag/Ag_2WO_4 Plasmonic Catalyst for Photocatalytic Reduction of CO_2 under Visible Light
作者: 何志桥; 童丽丽; 张志鹏; 陈建孟; 宋爽
刊名: 物理化学学报
ISSN: 1000-6818
出版年: 2015
卷: 31, 期:12, 页码:169-175,181
语种: 中文
中文关键词: 光催化 ; 二氧化碳还原 ; 甲烷 ; 钨酸银 ; 局域表面等离子共振
英文关键词: Photolysis ; Carbon dioxide reduction ; Methane ; Silver tungstate ; Localized surface plasma resonance
WOS学科分类: CHEMISTRY PHYSICAL
WOS研究方向: Chemistry
中文摘要: 转化CO_2为有机组分是缓解全球变暖和保障持续能源供给的有效方法之一. 采用简易的离子交换结合水合肼还原法制备了一系列不同晶相Ag_2WO_4载银(Ag/Ag_2WO_4)的等离子共振光催化剂, 并用X射线衍射(XRD)、X射线光电子能谱(XPS)、扫描电子显微镜-能量色散X射线光谱(SEM-EDS)、紫外-可见(UV-Vis)吸收光谱和比表面积测试对催化剂进行了表征. 较之Ag_2WO_4, Ag/Ag_2WO_4在可见光催化还原CO_2生成CH_4时显示了明显提高的量子产率(QY)、能量投入产出比(EROEI)、转换数(TON), 就Ag/alpha-Ag_2WO_4, Ag/beta-Ag_2WO_4和Ag/gamma-Ag_2WO_4而言, 最佳催化剂为Ag/beta-Ag_2WO_4, 其实际最佳Ag: Ag_2WO_4摩尔比为4: 96, 该催化剂还原CO_2为CH_4的QY、EROEI、TON和拟一级反应速率常数分别为0.145%、0.067%、9.61和1.96 * 10~(-6) min~(-1). 此外, 制备的等离子共振Ag/Ag_2WO_4光催化剂在可见光辐照下进行循环反应仍能保持稳定性. 局域表面等离子共振效应是强化Ag/Ag_2WO_4光催化剂活性和稳定性的主要原因.
英文摘要: The conversion of CO_2 into organic compounds is a promising method to mitigate global warming and assist in sustaining energy resources. A series of plasmonic photocatalysts, comprised of Ag supported on Ag_2WO_4 (Ag/Ag_2WO_4) with different crystalline phases, are fabricated by a facile ion-exchange method and subsequent reduction with hydrazine hydrate. The catalysts are characterized using X-ray diffraction (XRD) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), UV-Vis absorption spectroscopy, and Brunauer-Emmett-Teller analyses. Compared with Ag_2WO_4, the Ag/Ag_2WO_4exhibits a markedly improved quantum yield (QY), energy returned on energy invested (EROEI), and turnover number (TON) for CO_2 reduction to CH_4 under visible-light irradiation. Among Ag/alpha-Ag_2WO_4, Ag/beta-Ag_2WO_4, and Ag/gamma-Ag_2WO_4 catalysts, the highest activity for CO_2 photoreduction to CH_4 is obtained for Ag/beta-Ag_2WO_4 with an actual molar composition of 4% Ag and 96% Ag_2WO_4. Correspondingly the QY, EROEI, TON, and pseudo first-order rate constant are 0.145%, 0.067%, 9.61, and 1.96 * 10~(-6) min~(-1), respectively. Moreover, the plasmonic Ag/Ag_2WO_4 photocatalysts are stable after repeated reaction cycles under visible-light irradiation. It is proposed that the localized surface plasma resonance effect of surfacedeposited Ag contributed to the enhanced activities and stabilities of the Ag/Ag_2WO_4 photocatalysts.
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/150031
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作者单位: 浙江工业大学生物与环境工程学院, 杭州, 浙江 310032, 中国

Recommended Citation:
何志桥,童丽丽,张志鹏,等. Ag/Ag_2WO_4等离子体共振催化剂可见光催化还原CO_2[J]. 物理化学学报,2015-01-01,31(12):169-175,181
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