globalchange  > 气候变化事实与影响
CSCD记录号: CSCD:6087198
论文题名:
R1234ze(Z)在243.152~373.150 K内的饱和蒸汽压实验测量及拟合
其他题名: Saturation pressure measurement and correlation of cis-1,3,3,3-Tetrafluoropropene at temperatures ranging from 243.152 to 373.150 K
作者: 卓可凡; 赵延兴; 董学强; 公茂琼; 吴剑峰
刊名: 科学通报
ISSN: 0023-074X
出版年: 2017
卷: 62, 期:23, 页码:36-44
语种: 中文
中文关键词: 顺式-四氟丙烯 ; 饱和蒸汽压 ; 偏差 ; Wagner方程 ; 亥姆霍兹方程
英文关键词: R1234ze(Z) ; saturation pressure ; deviation ; Wagner equation ; Helmholtz equation
WOS学科分类: ENGINEERING INDUSTRIAL
WOS研究方向: Engineering
中文摘要: 顺式-四氟丙烯(cis-1,3,3,3-Tetrafluoropropene, R1234ze(Z))作为环境友好(温室效应潜能值GWP<1,臭氧消耗潜能值ODP=0),热力性能优异的新型工质在制冷、热泵及有机朗肯循环等领域受到越来越多的关注.本文采用两套高精度汽液相平衡装置测量了R1234ze(Z)在243.152~373.150 K内的63组饱和蒸汽压数据,本文的实验数据与Wagner方程拟合偏差均小于0.001 MPa,与REFPROP对比最大绝对偏差为0.0016 MPa,最大相对偏差为1.07%.结合文献数据采用Antoine方程、Wagner方程以及亥姆霍兹方程进行拟合,并对计算值和实验值的偏差进行分析,发现亥姆霍兹方程中起主导作用的是第2项,并由此建立对比温度和对比压力的近似线性关系,采用Wagner方程和最优项数为5项的亥姆霍兹方程拟合的平均绝对相对偏差分别为0.3105%和0.2813%,后者较前者拟合精度提高11.4%.
英文摘要: R1234ze(Z) (cis-1,3,3,3-Tetrafluoropropene), with the 10 d atmospheric life time and <1 global warming potential (GWP) value, has been investigated in refrigeration, heat pump, organic rankine cycle and other fields in recent years. In the work, some fundamental information about R1234ze(Z) was provided. At the same time, many researchers had investigated the heat transfer characteristic and frictional pressure drop of R1234ze(Z) for both the condensation and evaporation. The heat transfer coefficients of R1234ze(Z) are much higher than those of all the other refrigerants now used in heat pump application while the frictional pressure drop of R1234ze(Z) was a little higher than that of the conventional refrigerants. In conclusion, R1234ze(Z) is a very potential low-GWP and low-flammable refrigerant with high heat transfer coefficient while its frictional pressure drop is higher than conventional refrigerants. In this work, the saturation pressures of cis-1,3,3,3-tetrafluoropropene were investigated using two different apparatuses at temperatures rangingfrom 243.152 K to 373.150 K. The uncertainties of the temperature and pressure were less than 5 mK and 0.0007 MPa for one setups, and were less than 5 mK and 0.0005 MPa for another. The experimental data were compared with Fedele, Higashi, Katsuyuki and Refprop 9.1. Good agreements were found among them with the maximum deviation of 0.0016 MPa, and the maximum relative deviation of 1.07% comparing to Refprop 9.1. Using Antoine equation, Wagner equation and Helmholtz equation, the expermental data were regressed, and the average absolute relative deviation of the pressure are satisfactory. The relative deviation of the pressure were higher at lower temperature than that at higher temperature, due to the very low pressure at lower temperature. In the end, the Helmholtz equation was analyzed with various number of terms to regress the experimental data. An approximate linear correlation between the reduced pressure and the inverse reduced temperature was found by analyzing the dominant factor in the terms of the Helmholtz equation. The Helmholtz equation of three terms were good enough to represent the saturated vapor pressure of R1234ze(Z), and to get the best result, five terms were recommended in Helmholtz equation. The average absolute relative deviations of the pressures calculated by Wagner equation and Helmholtz equation with five terms are 0.3105% and 0.2813%, respectively.
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/152697
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作者单位: 中国科学院理化技术研究所, 航天低温推进剂技术国家重点实验室, 北京 100190, 中国

Recommended Citation:
卓可凡,赵延兴,董学强,等. R1234ze(Z)在243.152~373.150 K内的饱和蒸汽压实验测量及拟合[J]. 科学通报,2017-01-01,62(23):36-44
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