globalchange  > 气候变化事实与影响
CSCD记录号: CSCD:5562033
论文题名:
Zr_(46.9)Cu_(45.5)Al_(5.6)Y_(2.0)金属玻璃含B2-CuZr相内生复合材料的制备及其力学性能
其他题名: PREPARATION AND MECHANICAL PROPERTIES OF Zr_(46.9)Cu_(45.5)Al_(5.6)Y_(2.0) IN SITU BMG COMPOSITES WITH B2-CuZr PHASE
作者: 沈勇; 徐坚
刊名: 金属学报
ISSN: 0412-1961
出版年: 2015
卷: 51, 期:11, 页码:1407-1415
语种: 中文
中文关键词: 块体金属玻璃 ; 复合材料 ; 断裂韧性
英文关键词: B2-CuZr ; bulk metallic glass ; composite ; B2-CuZr ; fracture toughness
WOS学科分类: METALLURGY METALLURGICAL ENGINEERING
WOS研究方向: Metallurgy & Metallurgical Engineering
中文摘要: 通过增大铸造棒材直径来调整熔体的冷却速率,可在Zr_(46.9)Cu_(45.5)Al_(5.6)Y_(2.0)块体金属玻璃(BMG)中获得体积分数可变化的球形B2-CuZR相均匀分布于金属玻璃基体、并且具有较大尺寸的内生复合材料,其中含25%B2-CuZr相(体积分数)复合材料在压缩载荷下的塑性应变由单相金属玻璃的1.6%增大至6.5%,但在单向拉伸时样品没有观察到明显的延性应变.分析认为,复合材料在拉伸载荷下发生脆性断裂的本征原因在于CuZr相晶粒尺寸和间距与金属玻璃基体塑性区尺寸不满足尺寸匹配关系.在ZrCuAl合金中添加2%Y (原子分数)严重损伤了金属玻璃基体的断裂韧性和塑性区尺寸,与Zr_(46.9)Cu_(45.5)Al_(5.6)Y_(2.0)BMG相比,不含Y的Zr_(48)Cu_(45)Al_7 BMG样品可预制疲劳裂纹,三点弯曲实验测得断裂韧性为(623)MPa?m~(1/2),平面应变条件下在裂纹尖端的塑性区尺寸可达150 mum.
英文摘要: Bulk metallic glass (BMG) composites containing B2-CuZr phase are of interest due to they behave large plastic strain and apparent work hardening in tension. Nevertheless till now most BMG composites containing B2-CuZr phase are based on Cu_(47.5)Zr_(47.5)Al_5 or Zr_(48)Cu_(47.5)Al_4Co_(0.5) BMG, which has limited glass forming ability (GFA). The prepared sample size is small, which restricts their potential engineering structural applications. In this work, Zr-Cu-Al-Y quaternary system is selected due to its high GFA. By tuning composition close to CuZr alloy in Zr-Cu-Al-Y quaternary system, Zr_(46.9)Cu_(45.5)Al_(5.6)Y_(2.0) BMG is selected because it has proper GFA (critical diameter D_c=5 mm) and relatively large fracture toughness (K_Q=(493) MPa?m~(1/2)). By decreasing the cooling rates of the melt via increasing diameter of casting rods, large-sized in situ Zr_(46.9)Cu_(45.5)Al_(5.6)Y_(2.0) BMG composites containing 13% and 25% volume fractions spherical B2-CuZr phase were prepared in the casting rods with 6 and 7 mm in diameters, respectively. In compression testing, the in situ BMG composites containing 25%B2-CuZr phase promote multiple shear bands within glass matrix and remarkable global plastic deformation, accompanied by a large compressive plastic strain as 6.5%. Nevertheless in tension testing no obvious global ductility was achieved, which attributes to the low mode I fracture toughness and small plastic zone size (R_P=88 mum,R_P=(1/3pi)(K_Q/sigma_y)~2) of glass matrix. Three point bending test results show that Y has an adverse effect on the fracture toughness and plastic zone size of Zr-Cu-Al BMGs. In contrast to Zr_(46.9)Cu_(45.5)Al_(5.6)Y_(2.0) BMG, fatigue pre-cracked Zr_(48)Cu_(45)Al_7 BMG plate samples can be prepared and exhibit a high fracture toughness (K_Q=(623) MPa?m~(1/2)) and a large plastic zone size (R_P=150 mum) in plane strain state. Our results show that GFA and fracture toughness of glass matrix should be balanced when designing new BMG composites containing B2-CuZr phase.
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/156792
Appears in Collections:气候变化事实与影响

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作者单位: 中国科学院金属研究所, 沈阳材料科学国家(联合)实验室, 沈阳, 辽宁 110016, 中国

Recommended Citation:
沈勇,徐坚. Zr_(46.9)Cu_(45.5)Al_(5.6)Y_(2.0)金属玻璃含B2-CuZr相内生复合材料的制备及其力学性能[J]. 金属学报,2015-01-01,51(11):1407-1415
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