globalchange  > 气候变化与战略
DOI: 10.1002/2017GB005786
论文题名:
Comment on “The Effects of Secular Calcium and Magnesium Concentration Changes on the Thermodynamics of Seawater Acid/Base Chemistry: Implications for Eocene and Cretaceous Ocean Carbon Chemistry and Buffering” by Hain et al. (2015)
作者: Zeebe R.E.; Tyrrell T.
刊名: Global Biogeochemical Cycles
ISSN: 0886-6236
EISSN: 1944-9224
出版年: 2018
卷: 32, 期:5
语种: 英语
学科: calcium ; carbonic acid constants ; CO2 system ; magnesium ; reconstructions ; seawater
中文摘要: Hain et al. (2015, https://doi.org/10.1002/2014GB004986, hereafter H15) calculated effects of changing [Ca2+] and [Mg2+] on the equilibrium constants of the CO2-CaCO3 system in seawater based on a Pitzer ionic interaction model. We show here that critical results presented in H15 are fundamentally wrong. We therefore do not recommend using H15's stoichiometric equilibrium constants to correct for past changes in major-ion seawater composition. ©2018. American Geophysical Union. All Rights Reserved.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/160231
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作者单位: School of Ocean and Earth Science and Technology, University of Hawaii at Manoa, Honolulu, HI, United States; Ocean and Earth Science, University of Southampton, Southampton, United Kingdom

Recommended Citation:
Zeebe R.E.,Tyrrell T.. Comment on “The Effects of Secular Calcium and Magnesium Concentration Changes on the Thermodynamics of Seawater Acid/Base Chemistry: Implications for Eocene and Cretaceous Ocean Carbon Chemistry and Buffering” by Hain et al. (2015)[J]. Global Biogeochemical Cycles,2018-01-01,32(5)
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