DOI: 10.1016/j.atmosenv.2019.117178
论文题名: Determination of dicarboxylic acids in atmospheric aerosols using continuous aerosol sampler with on-line connected ion chromatography system
作者: Čapka L. ; Mikuška P. ; Křůmal K.
刊名: Atmospheric Environment
ISSN: 1352-2310
出版年: 2020
卷: 222 语种: 英语
英文关键词: Atmospheric thermodynamics
; Deionized water
; Gas chromatography
; Integrated circuits
; Ion chromatography
; Ions
; Mass spectrometry
; Oxalic acid
; CGU-ACTJU sampler
; Condensation growth
; Dicarboxylic acid
; Limits of detection
; On-line analysis
; On-line determination
; On-line preconcentration
; Pre-concentration
; Atmospheric aerosols
; deionized water
; dicarboxylic acid
; maleic acid
; malonic acid
; oxalic acid
; palmitic acid
; succinic acid
; aerosol
; chemical compound
; detection method
; ion chromatography
; sampler
; aerosol
; air analysis
; ambient air
; effluent
; ion chromatography
; limit of detection
; mass fragmentography
; priority journal
; temperature
; Brno
; Czech Republic
; Jihomoravsky
学科: Atmospheric aerosol
; CGU-ACTJU sampler
; Dicarboxylic acids
; Ion chromatography
; On-line analysis
中文摘要: The aim of the presented study was to use a recently developed CGU-ACTJU-IC system for on-line determination of dicarboxylic acids (DCAs) in aerosols over short time periods involving aerosol sampling into deionized water using a Condensation Growth Unit – Aerosol Counterflow Two-Jets Unit (CGU-ACTJU) sampler, quantitative preconcentration of analytes and determination by ion chromatography (IC). The parameters of automated on-line preconcentration method, using two parallel preconcentration columns and piston pump, were optimized. Limits of detection of studied DCAs, i.e., oxalic, malonic, succinic, glutaric/adipic, pimelic, azelaic and maleic acid, were determined to 0.27, 0.92, 1.74, 0.82, 1.17, 1.41 and 0.48 ng m−3, respectively. The optimized method was used for the analysis of DCAs in urban aerosol in Brno in two campaigns: from 5th to 9th December 2016 and from 12th to 21st July 2017. The results obtained by the developed method were compared with two reference methods including sampling of aerosols on filters and subsequent analysis of DCAs by gas chromatography with mass spectrometry (GC/MS) or IC. The presented study describes an alternative on-line method, compared to filter sampling, for monitoring of DCAs in atmospheric aerosols, allowing measurement with 1-h time resolution. © 2019 Elsevier Ltd Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/160637
Appears in Collections: 气候变化与战略
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作者单位: Institute of Analytical Chemistry of the Czech Academy of Sciences, Veveří 97, Brno, 602 00, Czech Republic
Recommended Citation:
Čapka L.,Mikuška P.,Křůmal K.. Determination of dicarboxylic acids in atmospheric aerosols using continuous aerosol sampler with on-line connected ion chromatography system[J]. Atmospheric Environment,2020-01-01,222