DOI: 10.1016/j.epsl.2021.117059
论文题名: First-principles investigation of equilibrium iron isotope fractionation in Fe1−xSx alloys at Earth's core formation conditions
作者: Pinilla C. ; de Moya A. ; Rabin S. ; Morard G. ; Roskosz M. ; Blanchard M.
刊名: Earth and Planetary Science Letters
ISSN: 0012821X
出版年: 2021
卷: 569 语种: 英语
中文关键词: core
; high pressure
; iron
; isotope fractionation
; sulfur
英文关键词: Iron
; Iron alloys
; Silicates
; Sulfur
; Condition
; Core
; Core-formation
; Earth's core formations
; Fe isotopes
; First-principles investigations
; Formation condition
; High pressure
; Iron isotopes
; Isotope fractionation
; Isotopes
; alloy
; core (planetary)
; high pressure
; iron
; isotopic fractionation
; sulfur
英文摘要: Iron is one of the most abundant non-volatile elements in the solar system. As a major component of planetary metallic alloys, its immiscibility with silicates plays a major role in planetary formation and differentiation. Information about these processes can be gained by studying the equilibrium Fe isotope fractionation between metal alloys and molten silicates at conditions of core formation. In particular, recent attention has been paid to 56Fe/54Fe equilibrium isotope fractionation at conditions relevant to Earth's core formation and the influence that light elements (O, H, C, Ni, Si and S) have had in this process. Most of these experimental studies relied on the measurement of Fe isotope fractionation from quenched phases of silicate melts and molten iron alloys. The experimental works are extremely challenging, and may suffer different drawbacks. To overcome this, we use ab-initio computational methods to perform a systematic study of the 56Fe/54Fe equilibrium isotope fractionation in molten and solid Fe1−xSx alloys at conditions of the core formation (60 GPa, 3000 K). We show for the first time, that equilibrium isotope fractionation factors from solid systems can be used as proxies for molten systems with differences between these two methods less than 0.01‰ at the relevant P-T conditions. Additionally, we discuss the effect of sulphur concentration on the equilibrium Fe isotope fractionation and show that although there are some structural changes due to atom substitutions, the wide range of studied concentrations produces β-factors that are constant within ∼0.02‰. Finally, we discuss the implications of our results for the interpretation of recent experiments and the understanding of core crystallisation processes. © 2021 Elsevier B.V. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/165632
Appears in Collections: 气候变化与战略
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作者单位: Departamento de Física y Geociencias, Universidad del Norte, Km 5 Via Puerto Colombia, Barranquilla, Colombia; Géosciences Environnement Toulouse, Université de Toulouse, CNRS, IRD, UPS, CNES, 14 avenue E. Belin, Toulouse, 31400, France; Institut de Minéralogie, de Physique des Matériaux, et de Cosmochimie (IMPMC), UMR CNRS 7590, Sorbonne Universités, Muséum National d'Histoire Naturelle, CP 52, 57 rue Cuvier, Paris, F-75231, France; Université Grenoble Alpes, CNRS, IRD, IFSTTAR, ISTerre, Grenoble, 38000, France; School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, United Kingdom
Recommended Citation:
Pinilla C.,de Moya A.,Rabin S.,et al. First-principles investigation of equilibrium iron isotope fractionation in Fe1−xSx alloys at Earth's core formation conditions[J]. Earth and Planetary Science Letters,2021-01-01,569