globalchange  > 气候变化与战略
DOI: 10.1016/j.scib.2020.09.016
论文题名:
Electrocatalytic water-splitting for the controllable and sustainable synthesis of deuterated chemicals
作者: Zhang B.; Qiu C.; Wang S.; Gao H.; Yu K.; Zhang Z.; Ling X.; Ou W.; Su C.
刊名: Science Bulletin
ISSN: 20959273
出版年: 2021
卷: 66, 期:6
起始页码: 562
结束页码: 569
语种: 英语
中文关键词: Deuterium labelling ; Electrocatalysis ; Green chemistry ; Selective deuteration ; Water splitting
英文关键词: Deuterium ; Efficiency ; Heavy water ; Hydrogen production ; Hydrogen storage ; Applied voltages ; Economic challenges ; Electrocatalytic ; Hydrogen evolution ; Hydrogen generations ; Reaction efficiency ; Value-added chemicals ; Water electrolysis ; Chemicals
英文摘要: Tandem water electrolysis for the transformation of universal feedstock to value-added chemicals integrated with hydrogen generation and in situ utilization is a promising approach to address the economic challenges of electrochemical hydrogen evolution and storage. Herein, we present the controllable electrocatalytic deuteration of halides using inexpensive and reusable heavy water (D2O) as a D-source for the preparation of valuable D-labelled chemicals and pharmaceuticals under mild conditions. This electrochemical deuteration method with high efficiency and selectivity furnishes a series of D-labelled chemicals and pharmaceuticals in high yields with excellent D-incorporation. The reaction efficiency and selectivity, that is, the precise substitution of deuterium atoms at different halogen positions, can be tuned by varying the applied voltages. The results show the great potential of green and economical electrocatalytic methods for producing value-added fine chemicals in addition to hydrogen evolution. © 2020 Science China Press
Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/170493
Appears in Collections:气候变化与战略

Files in This Item:

There are no files associated with this item.


作者单位: International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology of Ministry of Education, Institute of Microscale Optoelectronics, Shenzhen University, Shenzhen, 518060, China; College of Materials Science and Engineering, Shenzhen University, Shenzhen, 518060, China; School of Materials Science and Engineering, Ocean University of China, Qingdao, 266100, China; Department of Chemistry, Tsinghua University, Beijing, 100084, China

Recommended Citation:
Zhang B.,Qiu C.,Wang S.,et al. Electrocatalytic water-splitting for the controllable and sustainable synthesis of deuterated chemicals[J]. Science Bulletin,2021-01-01,66(6)
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Zhang B.]'s Articles
[Qiu C.]'s Articles
[Wang S.]'s Articles
百度学术
Similar articles in Baidu Scholar
[Zhang B.]'s Articles
[Qiu C.]'s Articles
[Wang S.]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Zhang B.]‘s Articles
[Qiu C.]‘s Articles
[Wang S.]‘s Articles
Related Copyright Policies
Null
收藏/分享
所有评论 (0)
暂无评论
 

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.