Carbon
; Carbon dioxide
; Catalyst activity
; Catalysts
; Chemisorption
; Copper
; High resolution transmission electron microscopy
; Hydrogenation
; Inductively coupled plasma
; Optical emission spectroscopy
; Synthesis gas manufacture
; Temperature programmed desorption
; Transmission electron microscopy
; X ray diffraction
; X ray photoelectron spectroscopy
; Catalyst characterization
; Inductively coupled plasma-optical emission spectrometry
; Linear relationships
; Methanol synthesis
; Promoter effect
; Reaction conditions
; Reaction temperature
; Slurry reactor
; Methanol
英文摘要:
This article describes the synthesis of methanol by the direct hydrogenation of CO2 over Cu/ZrO2 catalyst at different ZrO2 concentrations (5, 10, 15, 20 and 25 wt.%) in a three-phase phase reactor. The techniques of N2 adsorption/desorption, x-ray diffraction, x-ray photoelectron spectroscopy, transmission electron microscopy, temperature-programmed desorption by CO2, N2O chemisorption and inductively coupled plasma optical emission spectrometry were employed for catalyst characterization. At a reaction temperature of 180 °C, pressure of 3.0 MP and 0.020 g/mL of the catalyst, the conversion of CO2 and the yield of methanol were 10% and 25 g/kg.h, respectively. Surface area of the metallic copper was increased from 8.1 to 9.5 m2/g with the presence of ZrO2 from 5 to 15 wt.%. The methanol turnover frequency exhibited a linear relationship with ZrO2 concentration. Methanol synthesis rate was progressively increased with increasing fraction of dispersed copper. A comparative study with the literature revealed better activity of this novel catalyst at relatively low reaction conditions.
Din I.U.,Shaharun M.S.,Naeem A.,et al. Carbon nanofiber-based copper/zirconia catalyst for hydrogenation of CO2 to methanol[J]. Journal of CO2 Utilization,2017-01-01,21