DOI: 10.1016/j.jcou.2017.06.013
Scopus记录号: 2-s2.0-85021692665
论文题名: Two-dimensional zeolites: Adsorption of carbon dioxide on pristine materials and on materials modified by magnesium oxide
作者: Zukal A. ; Kubů M. ; Pastva J.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2017
卷: 21 起始页码: 9
结束页码: 16
语种: 英语
英文关键词: Carbon dioxide adsorption
; Magnesium oxide incorporation
; Two-dimensional zeolites
Scopus关键词: Adsorbents
; Adsorption
; Carbon dioxide
; Magnesia
; Magnesium
; Zeolites
; Adsorption capacities
; Adsorption heats
; Carbon dioxide adsorption
; CO2 adsorption
; Layered precursors
; Low pressures
; Pristine materials
; Temperature range
; Gas adsorption
英文摘要: Magnesium oxide has been introduced into zeolites MCM-22, MCM-36, IPC-3, IPC-3PI and ITQ-2 synthesized from 2D layered precursors MCM-22P and ICP-3P. Prepared materials were tested as carbon dioxide adsorbents in the temperature range from 0 °C to 60 °C. For parent zeolites, the IPC-3 has shown at 1 kPa the adsorption capacity (5.1 cm3/g STP), which was nearly two times higher than that of MCM-22 (2.7 cm3/g STP). Adsorption capacity of zeolites in the low pressure region markedly increased due to incorporation of magnesium oxide. The amount adsorbed on MgO-IPC-3 and MgO-MCM-22 at 1 kPa was enhanced to 11.4 and 13.7 cm3/g STP. Isosteric adsorption heats giving information on the energetics of CO2 adsorption were calculated. © 2017 Elsevier Ltd. All rights reserved.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/52665
Appears in Collections: 影响、适应和脆弱性
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Recommended Citation:
Zukal A.,Kubů M.,Pastva J.. Two-dimensional zeolites: Adsorption of carbon dioxide on pristine materials and on materials modified by magnesium oxide[J]. Journal of CO2 Utilization,2017-01-01,21