DOI: 10.1016/j.jcou.2016.02.003
Scopus记录号: 2-s2.0-84958168083
论文题名: Pd/C as a high efficient and reusable catalyst for cycloaddition of CO2 to epoxides
作者: Fu X. ; Zhou D. ; Wang K. ; Jing H.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2016
卷: 14 起始页码: 31
结束页码: 36
语种: 英语
英文关键词: Carbon dioxide
; Coupling reaction
; Cyclic carbonate
; Epoxide
; Palladium
Scopus关键词: Catalyst selectivity
; Catalysts
; Chemical reactions
; Palladium
; Coupling reaction
; Cyclic carbonates
; Epoxide
; High efficient
; High selectivity
; Palladium catalyst
; Reusable catalysts
; Tetrabutylammonium
; Carbon dioxide
英文摘要: Pd/C was found to be an excellent catalyst in the coupling reaction of carbon dioxide and epoxides with tetrabutylammonium iodide (TBAI) as cocatalyst and the corresponding cyclic carbonates were obtained in good yields and high selectivities. 3-Chloropropylene carbonate was synthesized under extremely mild conditions of room temperature and atmosphere. The proposed mechanism was also calculated and confirmed by DFT. The palladium catalyst could be simply recycled and reused for 5 times without significant loss of activity. © 2016 Elsevier Ltd. All rights reserved. 资助项目: National Natural Science Foundation of China
; National Natural Science Foundation of China
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/52920
Appears in Collections: 影响、适应和脆弱性