globalchange  > 影响、适应和脆弱性
DOI: 10.1016/j.jcou.2015.12.002
Scopus记录号: 2-s2.0-84954069976
论文题名:
Formation of dibutyl carbonate and butylcarbamate via CO2 insertion in titanium(IV) butoxide and reaction with n-butylamine This work is dedicated to the memory of Prof. M.D. Grillone and Prof. M. Schiavello.
作者: Parrino F.; Deiana C.; Chierotti M.R.; Martra G.; Palmisano L.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2016
卷: 13
起始页码: 90
结束页码: 94
语种: 英语
英文关键词: Carbamate ; CO2 insertion ; Dibutyl carbonate ; Titanium alkoxides
Scopus关键词: Carbonation ; Magnetic resonance spectroscopy ; Nuclear magnetic resonance spectroscopy ; Titanium ; Aliphatic amines ; Amine molecules ; Building blockes ; Carbamate ; N-butylamine ; Nucleophilic attack ; Titanium alkoxides ; Titanium butoxide ; Carbon dioxide
英文摘要: The species resulting from insertion of 12CO2 and 13CO2 into titanium(IV) butoxide is for the first time fully characterized by means of infrared and nuclear magnetic resonance spectroscopy. Results show formation of Ti-monobutylcarbonate, that easily undergoes nucleophilic attack by an aliphatic amine. The hydrolysis of the resulting species produces butylcarbamate and dibutylcarbonate as the only main products. Characterization results of the carbonate-like adduct, along with its reactivity with amine molecules open the route to new ways of CO2 utilization as building block for valuable organic compounds. © 2015 Elsevier Ltd. All rights reserved.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/52927
Appears in Collections:影响、适应和脆弱性

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Recommended Citation:
Parrino F.,Deiana C.,Chierotti M.R.,et al. Formation of dibutyl carbonate and butylcarbamate via CO2 insertion in titanium(IV) butoxide and reaction with n-butylamine This work is dedicated to the memory of Prof. M.D. Grillone and Prof. M. Schiavello.[J]. Journal of CO2 Utilization,2016-01-01,13
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