DOI: 10.1016/j.jcou.2014.04.001
Scopus记录号: 2-s2.0-84905593641
论文题名: A thermodynamic resolution of dimethyl carbonate decarboxylation and the first example of its reversibility: Dimethyl ether carboxylation
作者: Lacroix J.F. ; Soldera A. ; Lavoie J.M.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2014
卷: 7 起始页码: 46
结束页码: 50
语种: 英语
英文关键词: Carbon dioxide
; Dimethyl carbonate
; Dimethyl ether
; Heterogeneous catalysis
Scopus关键词: Carbon dioxide
; Catalysis
; Fuels
; Aliphatic ethers
; Dimethyl carbonate
; Dimethyl ethers
; Faujasites
; Fixed bed reactor
; Carboxylation
英文摘要: Dimethyl carbonate (DMC) decarboxylation and dimethyl ether (DME) carboxylation was found to be a system under equilibrium in which CO2 is the cornerstone. DMC decarboxylation to DME and CO2 was thermodynamically and kinetically resolved, which allowed obtaining conditions in which DME carboxylation is thermodynamically favourable. Subsequent demonstration of DME carboxylation represents the first example of CO 2 insertion in an aliphatic ether function. This study was carried out using a continuous fixed bed reactor loaded with zinc-exchanged faujasite catalyst, design to mimic the equilibrium mechanism of CO2 hydration by the enzyme carbonic anhydrase. © 2014 Elsevier Ltd. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/53005
Appears in Collections: 影响、适应和脆弱性
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Recommended Citation:
Lacroix J.F.,Soldera A.,Lavoie J.M.. A thermodynamic resolution of dimethyl carbonate decarboxylation and the first example of its reversibility: Dimethyl ether carboxylation[J]. Journal of CO2 Utilization,2014-01-01,7