DOI: 10.1016/j.jcou.2013.02.001
Scopus记录号: 2-s2.0-84883180283
论文题名: One-pot reaction of CO2, epichlorohydrin and amine to synthesize 4-(phenylamino)methyl-ethylene carbonate catalyzed by ionic liquids
作者: Wang B. ; Feng X. ; Zhang L. ; Yang S. ; Jiang X. ; Zhou J. ; Gao G.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2013
卷: 1 起始页码: 88
结束页码: 91
语种: 英语
英文关键词: CO2
; Cyclic carbonates
; Ionic liquid
; One-pot synthesis
Scopus关键词: Cyclic carbonates
; Epichlorohydrin
; One-pot reaction
; One-pot synthesis
; Reaction mechanism
; Reaction temperature
; Aniline
; Carbon dioxide
; Catalysts
; Ethylene
; Ionic liquids
英文摘要: Ionic liquids were firstly used as catalysts for one-pot synthesis of 4-(phenylamino)methyl-ethylene carbonate from CO2, epichlorohydrin and aniline without the utilization of any solvents or additives. The effects of the ratio of epichlorohydrin and aniline, catalyst amount, reaction temperature, time and initial CO2 pressure were investigated. The catalytic activity of the reaction was affected by the anions of ionic liquids and followed the order of Cl- > Br- > OAc - > BF4- > PF6-. The possible reaction mechanism was proposed based on the reaction results. © 2013 Elsevier Ltd. All rights reserved. 资助项目: National Natural Science Foundation of China
; National Natural Science Foundation of China
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/53051
Appears in Collections: 影响、适应和脆弱性
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Recommended Citation:
Wang B.,Feng X.,Zhang L.,et al. One-pot reaction of CO2, epichlorohydrin and amine to synthesize 4-(phenylamino)methyl-ethylene carbonate catalyzed by ionic liquids[J]. Journal of CO2 Utilization,2013-01-01,1