| DOI: | 10.1016/J.jcou.2013.03.003
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| Scopus记录号: | 2-s2.0-84883158646
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| 论文题名: | Electrochemical reduction of carbon dioxide to ethylene: Mechanistic approach |
| 作者: | Ogura K.
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| 刊名: | Journal of CO2 Utilization
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| ISSN: | 22129820
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| 出版年: | 2013
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| 卷: | 1 | | 起始页码: | 43
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| 结束页码: | 49
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| 语种: | 英语
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| 英文关键词: | Carbon dioxide
; Electrochemical reduction
; Energy carrier
; Heterogeneous inner-sphere reaction
; Three-phase interface
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| Scopus关键词: | Concentrated solution
; Conversion process
; Electrochemical reductions
; Energy carriers
; Inner spheres
; Metal electrodes
; Potassium halides
; Renewable energies
; Electrolytic reduction
; Ethylene
; Fossil fuels
; Metal halides
; Phase interfaces
; Carbon dioxide
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| 英文摘要: | It has been appraised that the world energy spending will more than double by 2050. The global energy depends mostly on fossil fuels at present, while the estimated amount of fossil-fuel deposits goes on decreasing. The greater part of fossil fuels may be exhausted within next hundred years. In view of this situation, the electrochemical and selective conversion process of CO 2 to ethylene that can be driven by the electricity derived from renewable energy is attractive, since CO2 can be utilized as an energy carrier regardless of fossil fuel. The developed CO2 conversion process takes place under rather specific conditions involving three-phase (gas/solution/solid) interface, concentrated solution of potassium halide, low pH, and copper or Cu(I) halide-confined metal electrode. Herein, the bases for leading to the augmentation of the efficiency and selectivity in the electrochemical reduction of CO2 to ethylene are discussed in association with the reduction pathway. © 2013 Elsevier Ltd. All rights reserved. |
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| 资源类型: | 期刊论文
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| 标识符: | http://119.78.100.158/handle/2HF3EXSE/53052
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| Appears in Collections: | 影响、适应和脆弱性
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| Recommended Citation: | |
Ogura K.. Electrochemical reduction of carbon dioxide to ethylene: Mechanistic approach[J]. Journal of CO2 Utilization,2013-01-01,1
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