DOI: 10.1111/gcb.12021
论文题名: Evaluation of photoacoustic infrared spectroscopy for simultaneous measurement of N2O and CO2 gas concentrations and fluxes at the soil surface
作者: Iqbal J. ; Castellano M.J. ; Parkin T.B.
刊名: Global Change Biology
ISSN: 13541013
出版年: 2013
卷: 19, 期: 1 起始页码: 327
结束页码: 336
语种: 英语
英文关键词: Carbon dioxide
; Gas chromatography
; Humidity
; Nitrous oxide
; Photacoustic infrared gas analyzer
Scopus关键词: carbon dioxide
; nitrous oxide
; accuracy assessment
; carbon dioxide
; concentration (composition)
; gas chromatography
; infrared spectroscopy
; nitrogen dioxide
; precision
; soil surface
; acoustics
; article
; chemistry
; gas chromatography
; infrared spectrophotometry
; methodology
; reproducibility
; soil
; Acoustics
; Carbon Dioxide
; Chromatography, Gas
; Nitrous Oxide
; Reproducibility of Results
; Soil
; Spectrophotometry, Infrared
英文摘要: Simultaneous measurement of N2O and CO2 flux at the soil surface with photoacoustic infrared spectroscopy (PAS) is gaining popularity due to portability, low maintenance, and ease-of-operation. However, the ability of PAS to measure N2O with accuracy and precision similar to gas chromatography (GC) is uncertain due to overlap in N2O, CO2, and H2O absorbance spectra combined with the large range in analyte concentrations. We tested the ability of six PAS units to simultaneously measure N2O and CO2 gas concentrations and fluxes with accuracy and precision similar to two GC units. We also evaluated H2O vapor and CO2 interferences with N2O measurement. The accuracy and precision of standard gas concentration measurements with PAS and GC were similar. High water vapor (~26 600 ppm) and CO2 concentrations (~4500 ppm) did not interfere with N2O measurement across the concentration range typically observed in static flux chambers at the soil surface (~0.5-3.0 ppm N2O). On average, N2O fluxes measured with the six PAS were 4.7% higher than one GC and 9.9% lower than the second GC. © 2012 Blackwell Publishing Ltd. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/62566
Appears in Collections: 影响、适应和脆弱性
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作者单位: Department of Agronomy, Iowa State University, Ames, IA 50011, United States; National Laboratory for Agriculture and the Environment, US Department of Agriculture, ARS, Ames, IA 50011, United States
Recommended Citation:
Iqbal J.,Castellano M.J.,Parkin T.B.. Evaluation of photoacoustic infrared spectroscopy for simultaneous measurement of N2O and CO2 gas concentrations and fluxes at the soil surface[J]. Global Change Biology,2013-01-01,19(1)