DOI: 10.1002/jgrd.50807
论文题名: CMAQ modeling and analysis of radicals, radical precursors, and chemical transformations
作者: Czader B.H. ; Li X. ; Rappenglueck B.
刊名: Journal of Geophysical Research Atmospheres
ISSN: 21698996
出版年: 2013
卷: 118, 期: 19 起始页码: 11376
结束页码: 11387
语种: 英语
英文关键词: CMAQ
; Houston
; radical precursors
; SHARP
Scopus关键词: Air quality
; Chemical analysis
; Formaldehyde
; Free radicals
; Ozone
; Ozone layer
; Photolysis
; Uncertainty analysis
; Weather forecasting
; CMAQ
; Community multi-scale air qualities
; Houston
; Meteorological condition
; Meteorological parameters
; Radical precursor
; SHARP
; Weather research and forecasting models
; Computer simulation
; air mass
; air quality
; atmospheric pollution
; concentration (composition)
; emission
; humidity
; hydrogen peroxide
; meteorology
; numerical model
; ozone
; pollutant removal
; radical
; transformation
; Texas
; United States
英文摘要: Air quality simulations were performed for the Houston-Galveston-Brazoria area for springtime conditions in May and June of 2009. Meteorological parameters predicted by Weather Research and Forecasting (WRF) model, for which data assimilation with recursive objective analysis was performed, are well simulated most of the time. The Community Multiscale Air Quality (CMAQ) model driven by meteorology from WRF simulates ozone and many other trace species, including radical precursors such as HCHO and HONO, with a satisfactory agreement with observations. While CMAQ satisfactorily captures the daily variations of the OH radical, it sometimes underestimates its high daytime values. Concentrations of HO2 are often underpredicted in polluted air masses and persistently severely underpredicted at low NOx conditions, when the Houston air is affected by marine air masses. In contrast, concentrations of H2 O2 and CH3 OOH are almost always overpredicted by the model, the overprediction occurs frequently in the polluted air and occurs always when marine air is encountered. Those mispredictions are consistent despite day-to-day variations in meteorological conditions and emissions and bring into question current representation of radical-related chemistry in the model as radical production and recirculation in the model is overtaken by termination processes and creation of more stable compounds, such as H2 O2 and CH3 OOH. Smaller model biases of H2 O2 and peroxides are associated with lower humidity. The relative importance of various photolysis processes as radical sources in the Houston atmosphere was also elucidated. Morning HO x formation is dominated by HONO while ozone contributes the most during midday. HONO contribution to HOx formation is more pronounced at the surface layer where most of it is formed, radical production from ozone is more important at elevated levels where higher concentrations of ozone are observed. Formaldehyde contributes up to 40% and also peaks during midday, but on days when high morning concentrations of formaldehyde are observed, its contribution to HOx in the morning exceeds that of ozone. Photolysis of H2 O2 is a minor contributor to radical levels. Key Points CMAQ simulates ambient concentrations of ozone well for Houston in May 2009 Modeling of radical precursors (HONO, HCHO) yield agreement with observations Uncertainties remains in predicting radicals and removal processes ©2013. American Geophysical Union. All Rights Reserved. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/63264
Appears in Collections: 影响、适应和脆弱性 气候减缓与适应
There are no files associated with this item.
作者单位: Department of Earth and Atmospheric Sciences, University of Houston, 312 Science and Research 1, Houston, TX 77004, United States
Recommended Citation:
Czader B.H.,Li X.,Rappenglueck B.. CMAQ modeling and analysis of radicals, radical precursors, and chemical transformations[J]. Journal of Geophysical Research Atmospheres,2013-01-01,118(19)