DOI: 10.1016/j.atmosenv.2015.08.077
Scopus记录号: 2-s2.0-84941553168
论文题名: Role of clay minerals in the formation of atmospheric aggregates of Saharan dust
作者: Cuadros J ; , Diaz-Hernandez J ; L ; , Sanchez-Navas A ; , Garcia-Casco A
刊名: Atmospheric Environment
ISSN: 0168-2563
EISSN: 1573-515X
出版年: 2015
卷: 120 起始页码: 160
结束页码: 172
语种: 英语
英文关键词: Clay
; Iberulite
; Mineral aerosol
Scopus关键词: Aerosols
; Agglomeration
; Aggregates
; Atmospheric aerosols
; Atmospheric chemistry
; Atmospheric structure
; Chemical analysis
; Clay
; Deposits
; Dust
; Electron probe microanalysis
; Kaolinite
; Microanalysis
; Minerals
; X ray diffraction
; Aggregation process
; Anthropic activity
; Atmospheric conditions
; Dust concentrations
; Iberulite
; Mineral aerosols
; Mineral composition
; Spherical particle
; Clay minerals
; aluminum silicate
; carbonic acid
; ethylene glycol
; iron oxide
; mineral
; silicon dioxide
; sulfate
; aerosol
; aerosol property
; aggregate
; atmospheric particle
; chemical analysis
; chemical composition
; clay mineral
; dry deposition
; dust
; mineralogy
; spatiotemporal analysis
; aerosol
; Article
; clay
; dust
; electron probe microanalysis
; evaporation
; microanalysis
; mineralogy
; priority journal
; scanning electron microscopy
; Spain
; transmission electron microscopy
; wettability
; X ray diffraction
; Andalucia
; Atlantic Ocean
; Canary Islands
; Granada [Andalucia]
; Iberian Peninsula
; Sahara
; Santa Cruz de Tenerife [(PRV) Canary Islands]
; Spain
; Tenerife
Scopus学科分类: Environmental Science: Water Science and Technology
; Earth and Planetary Sciences: Earth-Surface Processes
; Environmental Science: Environmental Chemistry
英文摘要: Saharan dust can travel long distances in different directions across the Atlantic and Europe, sometimes in episodes of high dust concentration. In recent years it has been discovered that Saharan dust aerosols can aggregate into large, approximately spherical particles of up to 100 μm generated within raindrops that then evaporate, so that the aggregate deposition takes place most times in dry conditions. These aerosol aggregates are an interesting phenomenon resulting from the interaction of mineral aerosols and atmospheric conditions. They have been termed "iberulites" due to their discovery and description from aerosol deposits in the Iberian Peninsula. Here, these aggregates are further investigated, in particular the role of the clay minerals in the aggregation process of aerosol particles. Iberulites, and common aerosol particles for reference, were studied from the following periods or single dust events and locations: June 1998 in Tenerife, Canary Islands; June 2001 to August 2002, Granada, Spain; 13-20 August 2012, Granada; and 1-6 June 2014, Granada. Their mineralogy, chemistry and texture were analysed using X-ray diffraction, electron microprobe analysis, SEM and TEM. The mineral composition and structure of the iberulites consists of quartz, carbonate and feldspar grains surrounded by a matrix of clay minerals (illite, smectite and kaolinite) that also surrounds the entire aggregate. Minor phases, also distributed homogenously within the iberulites, are sulfates and Fe oxides. Clays are apparently more abundant in the iberulites than in the total aerosol deposit, suggesting that iberulite formation concentrates clays. Details of the structure and composition of iberulites differ from descriptions of previous samples, which indicates dependence on dust sources and atmospheric conditions, possibly including anthropic activity. Iberulites are formed by coalescence of aerosol mineral particles captured by precursor water droplets. The concentration of clays in the iberulites is suggested to be the result of higher efficiency for clay capture than for the capture of larger mineral grains. The high hygroscopicity of clay minerals probably causes retention of water in the evaporation stage and some secondary minerals (mainly gypsum) are associated with clays. © 2015 Elsevier Ltd. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/81498
Appears in Collections: 气候变化事实与影响
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作者单位: Department of Earth Sciences, Natural History Museum, Cromwell Road, London, United Kingdom; IFAPA, Área de Recursos Naturales, Consejería de Agricultura, Pesca y Medio Ambiente, Junta de Andalucía, Granada, Spain; Departamento de Mineralogía y Petrología-IACT, Universidad de Granada-CISC, Granada, Spain
Recommended Citation:
Cuadros J,, Diaz-Hernandez J,L,et al. Role of clay minerals in the formation of atmospheric aggregates of Saharan dust[J]. Atmospheric Environment,2015-01-01,120