DOI: | 10.1016/j.atmosenv.2017.06.028
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Scopus记录号: | 2-s2.0-85021319971
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论文题名: | Artificial O3 formation during fireworks |
作者: | Fiedrich M; , Kurtenbach R; , Wiesen P; , Kleffmann J
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刊名: | Atmospheric Environment
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ISSN: | 0168-2563
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EISSN: | 1573-515X
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出版年: | 2017
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卷: | 165 | 起始页码: | 57
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结束页码: | 61
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语种: | 英语
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英文关键词: | Firework
; Interferences
; Nitrogen oxides
; Ozone
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Scopus关键词: | Combustion
; Molecular oxygen
; Nitrogen compounds
; Nitrogen oxides
; Ozone
; Photolysis
; Firework
; High-temperature combustion
; Interferences
; Known interferences
; Nitrogen dioxides
; Nitrogen monoxide
; Pyrotechnical materials
; UV absorption
; Explosives
; nitric oxide
; nitrogen dioxide
; oxygen
; ozone
; atmospheric chemistry
; combustion
; fire
; instrumentation
; nitrogen oxides
; oxygen
; ozone
; photolysis
; ultraviolet radiation
; volatile organic compound
; air monitoring
; analytical equipment
; Article
; combustion
; controlled study
; fire
; laboratory
; priority journal
; standard
; temperature
; titrimetry
; ultraviolet spectroscopy
; Germany
; North Rhine-Westphalia
; Wuppertal
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Scopus学科分类: | Environmental Science: Water Science and Technology
; Earth and Planetary Sciences: Earth-Surface Processes
; Environmental Science: Environmental Chemistry
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英文摘要: | In several previous studies emission of ozone (O3) during fireworks has been reported, which was attributed to either photolysis of molecular oxygen (O2) or nitrogen dioxide (NO2) by short/near UV radiation emitted during the high-temperature combustion of fireworks. In contrast, in the present study no O3 formation was observed using a selective O3-LOPAP instrument during the combustion of pyrotechnical material in the laboratory, while a standard O3 monitor using UV absorption showed extremely high O3 signals. The artificial O3 response of the standard O3 monitor was caused by known interferences associated with high levels of co-emitted VOCs and could also be confirmed in field measurements during New Year's Eve in the city of Wuppertal, Germany. The present results help to explain unreasonably high ozone levels documented during ambient fireworks, which are in contradiction to the fast titration of O3 by nitrogen monoxide (NO) in the night-time atmosphere. © 2017 Elsevier Ltd |
Citation statistics: |
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资源类型: | 期刊论文
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标识符: | http://119.78.100.158/handle/2HF3EXSE/82644
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Appears in Collections: | 气候变化事实与影响
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作者单位: | Institute for Atmospheric & Environmental Research, Bergische Universität Wuppertal, Gaußstraße 20, Wuppertal, Germany
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Recommended Citation: |
Fiedrich M,, Kurtenbach R,, Wiesen P,et al. Artificial O3 formation during fireworks[J]. Atmospheric Environment,2017-01-01,165
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