DOI: 10.1016/j.marpolbul.2015.09.026
Scopus记录号: 2-s2.0-84955697547
论文题名: A critical assessment of visual identification of marine microplastic using Raman spectroscopy for analysis improvement
作者: Lenz R. ; Enders K. ; Stedmon C.A. ; MacKenzie D.M.A. ; Nielsen T.G.
刊名: Marine Pollution Bulletin
ISSN: 0025-326X
EISSN: 1879-3363
出版年: 2015
卷: 100, 期: 1 起始页码: 82
结束页码: 91
语种: 英语
英文关键词: Photodegradation
; RAMAN
; Small microplastics
; Spectroscopy
Scopus关键词: Polypropylenes
; Spectroscopy
; Surface waters
; Chemical compositions
; Critical assessment
; Degradation state
; Microplastics
; North Atlantic
; RAMAN
; Raman micro spectroscopy
; Visual identification
; Photodegradation
; plastic
; polyethylene
; polymer
; polypropylene
; water pollutant
; acrylonitrile butadiene styrene
; microplastic
; organic matter
; plastic
; politef
; poly(methyl methacrylate)
; polyamide
; polycarbonate
; polyethylene
; polyethylene terephthalate
; polymer
; polypropylene
; polystyrene
; polyurethan
; polyvinylchloride
; unclassified drug
; analysis
; Atlantic Ocean
; chemistry
; environmental monitoring
; procedures
; Raman spectrometry
; water pollutant
; Article
; biota
; chemical composition
; concentration (parameters)
; controlled study
; degradation
; intermethod comparison
; microscopy
; particle size
; Raman spectrometry
; visual microscopy
; Atlantic Ocean
; Environmental Monitoring
; Plastics
; Polyethylene
; Polymers
; Polypropylenes
; Spectrum Analysis, Raman
; Water Pollutants
; critical analysis
; identification method
; photodegradation
; plastic waste
; Raman spectroscopy
; sea surface
; Atlantic Ocean
; Atlantic Ocean (North)
; Europe
Scopus学科分类: Agricultural and Biological Sciences: Aquatic Science
; Earth and Planetary Sciences: Oceanography
; Environmental Science: Pollution
英文摘要: Identification and characterisation of microplastic (MP) is a necessary step to evaluate their concentrations, chemical composition and interactions with biota. MP ≥ 10 μm diameter filtered from below the sea surface in the European and subtropical North Atlantic were simultaneously identified by visual microscopy and Raman micro-spectroscopy. Visually identified particles below 100 μm had a significantly lower percentage confirmed by Raman than larger ones indicating that visual identification alone is inappropriate for studies on small microplastics. Sixty-eight percent of visually counted MP (n = 1279) were spectroscopically confirmed being plastic. The percentage varied with type, colour and size of the MP. Fibres had a higher success rate (75%) than particles (64%). We tested Raman micro-spectroscopy applicability for MP identification with respect to varying chemical composition (additives), degradation state and organic matter coating. Partially UV-degraded post-consumer plastics provided identifiable Raman spectra for polymers most common among marine MP, i.e. polyethylene and polypropylene. © 2015 Elsevier Ltd. All rights reserved.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/85912
Appears in Collections: 过去全球变化的重建 全球变化的国际研究计划
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作者单位: National Institute of Aquatic Resources, Technical University of Denmark, DTU, Kavalergården 6, Charlottenlund, Denmark; Department of Micro- and Nanotechnology, Technical University of Denmark, DTU, Ørsteds Plads, Lyngby, Denmark
Recommended Citation:
Lenz R.,Enders K.,Stedmon C.A.,et al. A critical assessment of visual identification of marine microplastic using Raman spectroscopy for analysis improvement[J]. Marine Pollution Bulletin,2015-01-01,100(1)