globalchange  > 过去全球变化的重建
DOI: 10.1016/j.marpolbul.2015.09.026
Scopus记录号: 2-s2.0-84955697547
论文题名:
A critical assessment of visual identification of marine microplastic using Raman spectroscopy for analysis improvement
作者: Lenz R.; Enders K.; Stedmon C.A.; MacKenzie D.M.A.; Nielsen T.G.
刊名: Marine Pollution Bulletin
ISSN: 0025-326X
EISSN: 1879-3363
出版年: 2015
卷: 100, 期:1
起始页码: 82
结束页码: 91
语种: 英语
英文关键词: Photodegradation ; RAMAN ; Small microplastics ; Spectroscopy
Scopus关键词: Polypropylenes ; Spectroscopy ; Surface waters ; Chemical compositions ; Critical assessment ; Degradation state ; Microplastics ; North Atlantic ; RAMAN ; Raman micro spectroscopy ; Visual identification ; Photodegradation ; plastic ; polyethylene ; polymer ; polypropylene ; water pollutant ; acrylonitrile butadiene styrene ; microplastic ; organic matter ; plastic ; politef ; poly(methyl methacrylate) ; polyamide ; polycarbonate ; polyethylene ; polyethylene terephthalate ; polymer ; polypropylene ; polystyrene ; polyurethan ; polyvinylchloride ; unclassified drug ; analysis ; Atlantic Ocean ; chemistry ; environmental monitoring ; procedures ; Raman spectrometry ; water pollutant ; Article ; biota ; chemical composition ; concentration (parameters) ; controlled study ; degradation ; intermethod comparison ; microscopy ; particle size ; Raman spectrometry ; visual microscopy ; Atlantic Ocean ; Environmental Monitoring ; Plastics ; Polyethylene ; Polymers ; Polypropylenes ; Spectrum Analysis, Raman ; Water Pollutants ; critical analysis ; identification method ; photodegradation ; plastic waste ; Raman spectroscopy ; sea surface ; Atlantic Ocean ; Atlantic Ocean (North) ; Europe
Scopus学科分类: Agricultural and Biological Sciences: Aquatic Science ; Earth and Planetary Sciences: Oceanography ; Environmental Science: Pollution
英文摘要: Identification and characterisation of microplastic (MP) is a necessary step to evaluate their concentrations, chemical composition and interactions with biota. MP ≥ 10 μm diameter filtered from below the sea surface in the European and subtropical North Atlantic were simultaneously identified by visual microscopy and Raman micro-spectroscopy. Visually identified particles below 100 μm had a significantly lower percentage confirmed by Raman than larger ones indicating that visual identification alone is inappropriate for studies on small microplastics. Sixty-eight percent of visually counted MP (n = 1279) were spectroscopically confirmed being plastic. The percentage varied with type, colour and size of the MP. Fibres had a higher success rate (75%) than particles (64%). We tested Raman micro-spectroscopy applicability for MP identification with respect to varying chemical composition (additives), degradation state and organic matter coating. Partially UV-degraded post-consumer plastics provided identifiable Raman spectra for polymers most common among marine MP, i.e. polyethylene and polypropylene. © 2015 Elsevier Ltd. All rights reserved.
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资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/85912
Appears in Collections:过去全球变化的重建
全球变化的国际研究计划

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作者单位: National Institute of Aquatic Resources, Technical University of Denmark, DTU, Kavalergården 6, Charlottenlund, Denmark; Department of Micro- and Nanotechnology, Technical University of Denmark, DTU, Ørsteds Plads, Lyngby, Denmark

Recommended Citation:
Lenz R.,Enders K.,Stedmon C.A.,et al. A critical assessment of visual identification of marine microplastic using Raman spectroscopy for analysis improvement[J]. Marine Pollution Bulletin,2015-01-01,100(1)
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