| 项目编号: | 1760106
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| 项目名称: | DMREF: Collaborative Research: Programming mesostructured colloidal soft matter through complex quenching and annealing |
| 作者: | Roseanna Zia
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| 承担单位: | Stanford University
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| 批准年: | 2017
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| 开始日期: | 2017-09-01
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| 结束日期: | 2021-08-31
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| 资助金额: | 391203
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| 资助来源: | US-NSF
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| 项目类别: | Standard Grant
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| 国家: | US
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| 语种: | 英语
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| 特色学科分类: | Engineering - Chemical, Bioengineering, Environmental, and Transport Systems
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| 英文关键词: | colloidal material
; colloidal solid
; annealing
; fundamental understanding
; experiment
; new colloidal suspension
; thermal processing
; colloidal fluid
; structure
; colloidal system
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| 英文摘要: | The project supports integrated experiments, modeling and simulations to enable new ways of controlling material properties through thermal processing of colloidal materials. The goal is to develop new colloidal suspensions with temperature-sensitive interactions, and strategies by which they can be controllably processed into colloidal solids with desired structure and mechanical properties through quenching, annealing and tempering. The development of these new tools and the knowledge they create could lead to transformative new and scalable processing methods for colloidal materials with well-controlled and novel properties, and potentially impact a range of technologies including artificial tissue scaffolds, separation membranes, and inks for additive manufacturing. The research will be integrated with educational activities to train students in a new approach to making colloidal solids having unique structures and properties.
Thermal processing has long been known and employed for atomic and molecular materials, but has been elusive in colloidal materials because of a lack of colloidal systems with easily controlled temperature-responsive behavior, as well as a dearth of fundamental understanding for how the thermal history influences the development and arrest of structural morphologies and features in these systems. In this project, these challenges will be overcome using newly developed thermoresponsive colloids, and large-scale simulations and experiments that can rapidly probe the multitude of possible thermal histories and structures that emerge from them. Experiments and simulation will be combined to characterize how kinetic trajectories in thermodynamic variables map onto the relevant descriptors of emergent structural correlations and material properties including rheology. Leading efforts will establish categorical behavior for quenches in the homogeneous fluid phase, as well as in both metastable (binodal) and unstable (spinodal) regions of phase coexistence, followed on by more complex quenches involving annealing in more than one of these regions to seek out novel structures and rheology. Doing so will enable a more fundamental understanding for how kinetic processes of gelation, phase separation and glass formation compete in colloidal fluids to initiate, evolve and eventually arrest structure, and how the features of the arrested structure control the linear and non-linear mechanics of the material. This fundamental understanding will be used to develop a new conceptual framework for using thermal processing to design and engineer colloidal materials with well-specified structure and properties. |
| 资源类型: | 项目
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| 标识符: | http://119.78.100.158/handle/2HF3EXSE/89054
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| Appears in Collections: | 全球变化的国际研究计划
科学计划与规划
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| Recommended Citation: | |
Roseanna Zia. DMREF: Collaborative Research: Programming mesostructured colloidal soft matter through complex quenching and annealing. 2017-01-01.
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