| 项目编号: | 1663726
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| 项目名称: | Collaborative Research: Heterogeneous Chlorine Activation from Saline Playas |
| 作者: | Thomas Gill
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| 承担单位: | University of Texas at El Paso
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| 批准年: | 2017
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| 开始日期: | 2017-05-01
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| 结束日期: | 2020-04-30
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| 资助金额: | 18822
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| 资助来源: | US-NSF
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| 项目类别: | Continuing grant
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| 国家: | US
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| 语种: | 英语
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| 特色学科分类: | Geosciences - Atmospheric and Geospace Sciences
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| 英文关键词: | reactive chlorine
; chlorine atom
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| 英文摘要: | Droughts mobilize natural dust from salt playas that can react with nitrogen oxides, criteria pollutants that are emitted by combustion sources. This reaction releases chlorine atoms that are potent atmospheric oxidants but are neglected in models used to assess regional air quality because of lack of measurements. The proposal will measure the fundamental rate constants of real-world playa dust particles with nitrogen oxides to enable robust assessments of regional air quality impacts in salt playas regions such as Texas.
Reactive chlorine (Cl) atoms when activated can serve as potent atmospheric oxidants that would effect lifetimes of greenhouse gases like methane and also tropospheric ozone abundance. The proposal hypothesizes that wind blown chloride-containing dust from dried saline lake beds (playas) can be converted to nitryl-chloride (ClNO2) by heterogeneous reactions with gaseous dinitrogen pentoxide (N2O5). The ClNO2 photolysis produces Cl atoms that could alter the ozone production photochemistry and the methane lifetime significantly. The research will measure the kinetics of ClNO2 production from reactions of salt with N2O5 in a trace gas-aerosol flow reactor. Chemical ionization mass spectrometry will be used to monitor ClNO2 in the reactor and the playa dusts will be analyzed using single-particle mass spectrometry, ion chromatography and X ray diffraction. The in depth analysis of the chemical and atmospheric conditions under which chlorine can be released from the saline playas will provide a mechanistic framework that could be implemented in chemistry-climate and air-quality models to make more robust predictions and assessments. |
| 资源类型: | 项目
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| 标识符: | http://119.78.100.158/handle/2HF3EXSE/90252
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| Appears in Collections: | 全球变化的国际研究计划
科学计划与规划
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| Recommended Citation: | |
Thomas Gill. Collaborative Research: Heterogeneous Chlorine Activation from Saline Playas. 2017-01-01.
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