| DOI: | 10.2172/1131324
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| 报告号: | None
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| 报告题名: | Chemical Fixation of CO{sub 2} to Acrylates Using Low-Valent Molybdenum Sources |
| 作者: | Bernskoetter, Wesley
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| 出版年: | 2013
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| 发表日期: | 2013-09-30
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| 国家: | 美国
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| 语种: | 英语
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| 中文主题词: | 碳
; 二氧化碳
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| 主题词: | CARBON
; CARBON DIOXIDE
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| 英文摘要: | The kinetic, mechanistic, and reactivity experiments to access the viability and possible reaction design of coupling of carbon dioxide and ethylene at a zerovalent molybdenum for the production of acrylates are described. A general model of the reaction mechanism has been outlined, including assessment of the rate limiting step in the reaction. Kinetic and computational data have valuated the influence of a range of tridentate ligand platforms on the rate of coupling. An in situ reduction and acrylate formation activity screen protocol has also been developed to aid in the technology development of this process. Portions of descriptions of the research products presented here have also been adapted with permission from journal publications. |
| URL: | http://www.osti.gov/scitech/servlets/purl/1131324
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| Citation statistics: |
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| 资源类型: | 研究报告
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| 标识符: | http://119.78.100.158/handle/2HF3EXSE/40973
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| Appears in Collections: | 过去全球变化的重建
影响、适应和脆弱性
科学计划与规划
气候变化与战略
全球变化的国际研究计划
气候减缓与适应
气候变化事实与影响
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| 1131324.pdf（869KB） | 研究报告 | -- | 开放获取 | | View
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| Recommended Citation: | |
Bernskoetter, Wesley. Chemical Fixation of CO{sub 2} to Acrylates Using Low-Valent Molybdenum Sources. 2013-01-01.
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