DOI: 10.1016/j.jcou.2015.02.002
Scopus记录号: 2-s2.0-84924907867
论文题名: Efficiency of DBU/iodine cooperative dual catalysis for the solvent-free synthesis of five-membered cyclic carbonates under atmospheric CO2 pressure
作者: Coulembier O. ; Moins S. ; Lemaur V. ; Lazzaroni R. ; Dubois P.
刊名: Journal of CO2 Utilization
ISSN: 22129820
出版年: 2015
卷: 10 起始页码: 7
结束页码: 11
语种: 英语
英文关键词: CO2
; DBU
; Epoxide
; Iodine
; Organocatalysis
Scopus关键词: Catalysis
; Iodine
; Reaction kinetics
; Synthesis (chemical)
; Cooperative works
; Coupling reaction
; Cyclic carbonates
; DBU
; Dual catalysis
; Epoxide
; Organocatalysis
; Solvent free synthesis
; Carbon dioxide
英文摘要: The DBU·I2 dual catalyst is shown to have a very high activity for the coupling reaction of CO2 and various (bis)oxiranes. The cooperative work of both DBU and iodine is tolerant to water and allows performing the cyclo-addition of carbon dioxide in very mild conditions of pressure (pCO2 = 1 bar) and in total absence of organic solvent. © 2015 Elsevier Ltd. Citation statistics:
资源类型: 期刊论文
标识符: http://119.78.100.158/handle/2HF3EXSE/52973
Appears in Collections: 影响、适应和脆弱性
There are no files associated with this item.
Recommended Citation:
Coulembier O.,Moins S.,Lemaur V.,et al. Efficiency of DBU/iodine cooperative dual catalysis for the solvent-free synthesis of five-membered cyclic carbonates under atmospheric CO2 pressure[J]. Journal of CO2 Utilization,2015-01-01,10